Palladium catalyzed selective arylation of B(4)-H of o-carboranes with potassium aryltrifluoroborate

被引：1

作者：

Teng, Chao-Chao ^{[1
,2
]}

Guo, Yan ^{[3
]}

Cao, Ke ^{[1
,2
,3
]}

Yang, Han-Bo ^{[1
,2
]}

Jiang, Qi-Jia ^{[1
,2
]}

Zhu, Dao-Yong ^{[4
,5
]}

Wang, Shao-Hua ^{[4
,5
]}

机构：

[1] Southwest Univ Sci & Technol, State Key Lab Environm Friendly Energy Mat, 59 Qinglong Rd, Mianyang 621010, Sichuan, Peoples R China

[2] Southwest Univ Sci & Technol, Sch Mat & Chem, 59 Qinglong Rd, Mianyang 621010, Sichuan, Peoples R China

[3] Sichuan Sci City Hosp, Dept Oncol, Mianyang 621000, Sichuan, Peoples R China

[4] Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China

[5] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2024年 / 1008卷

基金：

中国国家自然科学基金;

关键词：

Carborane; B -H activation; Selective arylation; Potassium phenyltrifluoroborate; B-H ACTIVATION; AMIDATION; EMISSION; BONDS;

D O I：

10.1016/j.jorganchem.2024.123051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A palladium catalyzed selective arylation of B(4) -H of 9-amide-o-carborane with potassium aryltrifluoroborate has been developed. A series of B(4)-Ar-B(9)-amide-o-carborane derivatives decorated with diverse active groups have been synthesized with moderate to good yields as well as excellent selectivity. This work represents an unprecedented protocol for selective arylation of o-carboranes with potassium aryltrifluoroborates.

引用

页数：7

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