CO2-induced gate-opening structural transition process of a porous coordination polymer revealed by solid-state 13C NMR

被引：1
|
作者：
Kurihara, Takuya [1 ]
Souri, Yue [1 ]
Inukai, Munehiro [2 ]
Mizuno, Motohiro [1 ,3 ,4 ]
机构：
[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Mat Chem, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
[2] Tokushima Univ, Grad Sch Technol Ind & Social Sci, 2-1 Minami Josanjima Cho, Tokushima 7708506, Japan
[3] Kanazawa Univ, Nanomat Res Inst, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
[4] Kanazawa Univ, Inst Frontier Sci Initiat, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 38期
关键词：
METAL-ORGANIC FRAMEWORKS; BREATHING TRANSITIONS; ADSORPTION; DYNAMICS; SPECTROSCOPY; MECHANISM; INSIGHTS;
D O I：
10.1039/d4cc01180e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study investigates the gate-opening closed-to-open-pore structural transition of a porous coordination polymer induced by CO2 adsorption. Solid-state( 13)C NMR examination of adsorbed CO2 and framework dynamics reveals the surface adsorption state of the closed structure below the transition pressure and an intermediate structure during the transition process.
引用
收藏
页码：5074 / 5077
页数：4
相关论文
共 50 条
  • [31] Structural characterization of supramolecular assemblies by 13C spin dilution and 3D solid-state NMR
    Habenstein, Birgit
    Loquet, Antoine
    Giller, Karin
    Becker, Stefan
    Lange, Adam
    JOURNAL OF BIOMOLECULAR NMR, 2013, 55 (01) : 1 - 9
  • [32] Assessment of thermal evolution of kerogen geopolymers with their structural parameters measured by solid-state 13C NMR spectroscopy
    Wei, ZB
    Gao, XX
    Zhang, DJ
    Da, J
    ENERGY & FUELS, 2005, 19 (01) : 240 - 250
  • [33] Structural aspects of low-molecular-weight azocellulose polymers:: A solid-state 13C NMR study
    Yang, SZ
    Jacob, MM
    Li, L
    Cholli, AL
    Kumar, J
    NMR SPECTROSCOPY OF POLYMERS IN SOLUTION AND IN THE SOLID STATE, 2003, 834 : 58 - 70
  • [34] Photocatalytic degradation of highly refractive phenolic polymer Mechanistic insights as revealed by Electron Spin Resonance (ESR) and solid-state 13C NMR spectroscopy
    Sundarapandiyan, Sundaramoorthy
    Renitha, Thankaswamy Shiny
    Sridevi, Janardhanam
    Saravanan, Palanivel
    Chandrasekaran, Bangaru
    Raju, Guntamadugu Bhaskar
    CHEMICAL ENGINEERING JOURNAL, 2017, 313 : 1112 - 1121
  • [35] Structural characterization of supramolecular assemblies by 13C spin dilution and 3D solid-state NMR
    Birgit Habenstein
    Antoine Loquet
    Karin Giller
    Stefan Becker
    Adam Lange
    Journal of Biomolecular NMR, 2013, 55 : 1 - 9
  • [36] Influence of Process Parameters on the Hydrothermal Carbonization of Olive Tree Trimmings: A 13C Solid-State NMR Study
    Calucci, Lucia
    Forte, Claudia
    APPLIED SCIENCES-BASEL, 2023, 13 (03):
  • [37] n-Pentane carbonylation with CO on sulfated zirconia:: an in situ solid-state 13C NMR study
    Luzgin, MV
    Stepanov, AG
    Shmachkova, VP
    Kotsarenko, NS
    MENDELEEV COMMUNICATIONS, 2001, (01) : 23 - 25
  • [38] A structural and dynamic study of poly(vinyl alcohol) in the gel state by solid-state 13C NMR and 1H pulse NMR
    Kanekiyo, M
    Kobayashi, M
    Ando, I
    Kurosu, H
    Ishii, T
    Amiya, S
    JOURNAL OF MOLECULAR STRUCTURE, 1998, 447 (1-2) : 49 - 59
  • [39] Structural study of poly(vinyl alcohol) in the gel state by high-resolution solid-state 13C NMR spectroscopy
    Kobayashi, Masatoshi
    Ando, Isao
    Ishii, Takahiro
    Amiya, Shigetoshi
    Macromolecules, 1995, 28 (19):
  • [40] Chemical reactions in poly(acrylonitrile-co-itaconic acid) during stabilization as revealed by solid-state NMR spectroscopy and 13C isotope labeling
    Ma, Jiayang
    Zheng, Zhaoxi
    Tang, Yijing
    Nagashima, Hiroki
    Miyoshi, Toshikazu
    CARBON, 2023, 215
12345