Recent advancements of electrochemical attenuated total reflection surface-enhanced infrared absorption spectroscopy

被引:3
|
作者
Chao, Yang [1 ]
Li, Hong [1 ]
Jiang, Tian-Wen [1 ]
Huang, Jia-Ao [1 ]
Ma, Xian-Yin [1 ]
Jiang, Kun [1 ]
Cai, Wen-Bin [1 ]
机构
[1] Fudan Univ, Collaborat Innovat Ctr Chem Energy Mat, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200438, Peoples R China
基金
国家重点研发计划;
关键词
ATR-SEIRAS; In situ characterization; Electrochemical systems; Structure-performance relation; Reaction mechanism;
D O I
10.1016/j.coelec.2024.101509
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electrochemical attenuated total reflection surface-enhanced infrared absorption spectroscopy (EC-ATR-SEIRAS) is a powerful analytical tool to obtain molecular-level structural information at the electrode-electrolyte interface towards a better mechanistic understanding of electrochemical processes. In this minireview, we highlight the latest research progress of EC-ATR-SEIRAS over the past two years, in terms of technical innovations in IR elements, flow cells, detection sensitivity and time resolution as well as selected applications in studying electrocatalysis, biosensing and electroplating. Coupling ECATR-SEIRAS with other spectroelectrochemical methods is also discussed. And our perspectives on developing EC-ATRSEIRAS in the near future are put forward in the end.
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页数:8
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