Hydrodesulfurization Catalysts from Aluminium-Containing Waste

被引：1

作者：

Yunusov, M. P. ^{[1
]}

Gulomov, Sh. ^{[2
]}

Nasullayev, K. A. ^{[1
]}

Turdiyeva, D. P. k. ^{[1
]}

Isayeva, N. F. ^{[1
]}

Abdurakhmanova, I. S. k. ^{[1
]}

Mustafayev, B. D. ^{[1
]}

Murzin, D. Yu. ^{[3
]}

机构：

[1] Uzbek Res Chem & Pharmaceut Inst, 40 Durmon St, Tashkent 100125, Uzbekistan

[2] Tashkent Inst Chem Technol, Tashkent 100011, Uzbekistan

[3] Abo Akad Univ, Henriksgatan 2, Turku 20500, Finland

来源：

CATALYSIS LETTERS | 2024年 / 154卷 / 08期

关键词：

Catalysts; Hydrodesulfurization; atomic layer deposition; Alumina waste; NIMO/ALUMINA CATALYSTS; RAMAN; HYDRODEOXYGENATION; PERFORMANCE; PHOSPHORUS; SUPPORT; ACID;

D O I：

10.1007/s10562-024-04685-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A possibility of using aluminum hydroxide, a product of processing of the adsorbent that lost its sorption activity in purification of a polyethylene solution cyclohexane, was demonstrated in the synthesis of aluminum kaolin borate supports for hydrodesulfurization catalysis in oil refining. The influence of typical impurities V, Ti and Na in the composition of the spent adsorbent on the physicochemical and catalytic properties of supports and catalysts was determined. Alumina-kaolin-borate catalyst carriers with the Ti content of approx. 0.2% have been prepared by atomic layer deposition (ALD) of TiCl4 onto the granules. A positive effect of molecular layering with TiO2 has been revealed by temperature programmed reduction and oxidation in combination with hydrodesulphurization activity testing.

引用

页码：4409 / 4421

页数：13

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