Hydrothermal Synthesis, Crystal Structure, Magnetic Properties and Network Topology of a Novel Binuclear Co(Ⅱ) Coordination Polymer∞~1[Co2(4,4'-bpy)2(L)4](bpy = Bipyridine, HL = 2-Fluorbenzoic Acid)

被引：0

作者：

HU Ling-Xia ^{[1
]}

ZHANG Bi-Song ^{[1
]}

WU Chang-Sheng ^{[1
]}

HUANG Dong-Wei ^{[1
]}

QIU Jian-Ping ^{[1
]}

机构：

[1] College of Pharmaceutics and Material Engineering Jinhua Polytechnic

来源：

结构化学 | 2015年 / 34卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Co(Ⅱ) complex; coordination polymer; crystal structure; magnetic properties;

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

One novel binuclear Co(Ⅱ) coordination polymer 1[Co2(4,4’-bpy)2(L)4](1, bpy = bipyridine, HL = 2-fluorbenzoic acid) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR and X-ray single-crystal diffraction. Complex 1 crystallizes in the monoclinic system, space group P21/c with a = 11.163(2), b = 21.943(4), c = 9.6381(19)?, β = 113.92(3)°, V = 2158.2(7) ?, Z = 4, Dc = 1.518 g/cm3, Mr = 493.31, F(000) =1004, R = 0.0303 and w R = 0.0808 for 3614 observed reflections(I > 2σ(I)). Complex 1 exhibits a 3D Schlafli symbol(4.62)(4.66.83) topological framework, and the magnetic characterization shows weak antiferromagnetic coupling exchange between two Co ions.

引用

页码：953 / 959

页数：7

共 50 条

[41] Synthesis, crystal structure, and magnetic property of a novel 2D polymer [Co(PDQ(4,4-bpy)](CH3OH)
Xie, CZ
Zhang, BF
Liu, XW
Wang, XQ
Kou, HZ
Shen, GQ
Shen, DZ
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (09) : 1037 - 1040
[42] A spin-crossover iron(II) coordination polymer with the 8-aminoquinoline ligand:: synthesis, crystal structure and magnetic properties of [Fe(aqin)2(4,4′-bpy)](ClO4)2 • 2EtOH (aqin=8-aminoquinoline, 4,4′-bpy=4,4′-bipyridyl)
Genre, Caroline
Matouzenko, Galina S.
Jeanneau, Erwann
Luneau, Dominique
NEW JOURNAL OF CHEMISTRY, 2006, 30 (11) : 1669 - 1674
[43] A new one-dimensional coordination polymer containing a μ-[N(CN)2]- bridging ligand.: Synthesis, crystal structure and magnetic properties of Mn[N(CN)2]2(2,4′-bpy)2(2,4′-bpy=2,4′-bipyridine)
Liu, CM
Zhang, DQ
Zhu, DB
Jin, XL
TRANSITION METAL CHEMISTRY, 2003, 28 (03) : 336 - 338
[44] Hydrothermal Synthesis, Crystal Structure and Optical Property of A 2-D Organic-Inorganic Compound Ni(V2W4O19)(bpy)(Hbpy)2 (bpy=4,4′-Bipyridine)
Wang, Chong-Chen
ASIAN JOURNAL OF CHEMISTRY, 2009, 21 (06) : 4919 - 4926
[45] Syntheses and structure characterization of inorganic/organic coordination polymers:: Ag(dpa), Co(O3PH)(4,4′-bpy)(H2O), Zn(O3PH)(4,4′-bpy)0.5 and Mn[O2PH(C6H5)]2(4,4′-bpy) (dpa=2,2′-dipyridylamine; 4,4′-bpy=4,4′-bipyridine)
Liao, JH
Chen, PL
Hsu, CC
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2001, 62 (9-10) : 1629 - 1642
[46] Crystal structure of [Ru(bpy)(2)(CO)(eta(1)-C(O)OH)](+) (bpy=2,2'-bipyridine) as a key intermediate in CO2/CO conversion
Toyohara, K
Nagao, H
Adachi, T
Yoshida, T
Tanaka, K
CHEMISTRY LETTERS, 1996, (01) : 27 - 28
[47] Structural, Electronic, and Acid/Base Properties of [Ru(bpy)2(bpy(OH)2)]2+ (bpy = 2,2′-Bipyridine, bpy(OH)2 = 4,4′-Dihydroxy-2,2′-bipyridine) (vol 50, pg 2754, 2011)
Klein, Samantha
Dougherty, William G.
Kassel, W. Scott
Dudley, Timothy J.
Paul, Jared J.
INORGANIC CHEMISTRY, 2013, 52 (01) : 528 - 528
[48] A novel two-dimensional rectangular network.: Synthesis and structure of {[Cu(4,4′-bpy)(pyz)(H2O)2][PF6]2}n (4,4′-bpy equals 4,4′-bipyridine, pyz equals pyrazine)
Tong, ML
Chen, XM
Yu, XL
Mak, TCW
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (01): : 5 - 6
[49] Coordination polymers of cobalt(II):: [Co(4,4′-bpy)2(O2CCF3)2]n and [Co(4,4′-bpy)(O2CCH3)2(H2O)2]n
Zhang, YS
Enright, GD
Breeze, SR
Wang, SN
NEW JOURNAL OF CHEMISTRY, 1999, 23 (06) : 625 - 628
[50] A new one-dimensional coordination polymer containing a μ-[N(CN)2]− bridging ligand. Synthesis, crystal structure and magnetic properties of Mn[N(CN)2]2-(2,4′-bpy)2 (2,4′-bpy = 2,4′-bipyridine)
Cai-Ming Liu
De-Qing Zhang
Dao-Ben Zhu
Xianglin Jin
Transition Metal Chemistry, 2003, 28 : 336 - 338

← 1 2 3 4 5 →