Syntheses and Crystal Structures of Cobalt(II) Chloride Complexes of 1,3-Bis(pyridyl-4-ylthio)propan-2-one

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WU BenLai WU MingYan GONG YaQiong CHEN BaiQuan HONG MaoChun State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China [350002 ]
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结构化学 | 2006年 / 05期
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O621.25 [];
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摘要：
Reactions of 1,3-bis(pyridyl-4-ylthio)propan-2-one L and CoCl26H2O under dif- ferent conditions gave two new cobalt(II)-chloride-L complexes with distinct structures. Complex [Co(L)2Cl2]0.5CH3OH}n 1 prepared by solvothermal treatment is a 3D network, whereas complex {[Co3(L)2Cl6(DMF)4]2CH3OHH2O} 2 obtained in DMF-diethyl ether system is a discrete acyclic trimer. Crystal data for 1: space group Ibca, a = 15.993(4), b = 18.454(5), c = 21.506(6) , V = 6347(3) 3, Z = 8, Dc = 1.462 g/cm3, μ = 1.005 mm1, F(000) = 2864, C26.5H26Cl2CoN4O2.5S4, Mr = 698.58, the final R = 0.0499 and wR = 0.1024. Crystal data for 2: space group P1, a = 9.9177(6), b = 11.0871(4), c = 15.5490(12) , α = 83.1834(14), β = 88.910(13), γ = 71.096(11)o, V = 1605.8(2) 3, Z = 1, Dc = 1.362 g/cm3, μ = 1.194 mm1, F(000) = 677, C40H62Cl6Co3N8O9S4, Mr = 1316.71, the final R = 0.0666 and wR = 0.1575.
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页码：511 / 516
页数：6
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