Synthesis and Crystal Structure of 5,5'-Bis(4-hydroxylphenyl)diazo-dipyrromethane

被引：2
|
作者：
史红梅 [1 ]
尹振明 [1 ]
机构：
[1] Tianjin Key Laboratory of Structure and Performance for Functional Molecules
[2] Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry,Ministry of Education  3. College of Chemistry,Tianjin Normal University
来源：
结构化学 | 2013年 / 32卷 / 07期
关键词：
5; 5; -bisdiazo-dipyrromethane; hydrogen-bonded self-assembly; porous;
D O I：
暂无
中图分类号：
O626 [杂环化合物];
学科分类号：
070303 ; 081704 ;
摘要：
A new 5,5’ -bisdiazo-dipyrromethane, compound 2, has been synthesized and cha- racterized. The crystal of 2 is of monoclinic, space group P21/c with a = 16.3185(10), b = 20.8225(13), c = 18.5985(11) , β = 114.5280(10)°, V = 5749.3(6) 3 , Z =8, C25H26N6O2 , Mr = 442.52, Dc = 1.022 g/cm, F(000) = 1872, μ(MoKα) = 0.068 mm -1 . The final R = 0.0469 and wR = 0.1143 for 10119 observed reflections with I > 2σ(I), and R = 0.0677 and wR = 0.1231 for all reflections. The title compound prefers to form interlocked type dimer through quadruple N-H N hydrogen bonds. The dimers self-assemble into a porous 3-D structure through O-H O and C-H N hydrogen bonds.
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收藏
页码：1093 / 1099
页数：7
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