Azo Bond Reduction of N,N-diaryl Adipyl Bis-azo Compounds with Hydrazine Hydrate

被引：0

作者：

姜小莹 ^{[1
]}

王洪亮 ^{[2
]}

乔梅英 ^{[1
]}

王丙星 ^{[3
]}

机构：

[1] College of Chemistry and Chemical Engineering, Henan Institute of Science and Technology

[2] College of Resources and Environment, Henan Institute of Science and Technology

[3] College of Chemistry and Chemical Engineering, Harbin Normal University

来源：

Chinese Journal of Structural Chemistry | 2012年 / 31卷 / 06期

关键词：

N; N’-diaryl adipyl bis-azo compounds; N’-diaryl adipyl dihydrazine; hydrazine hydrate; selective reduction;

D O I：

暂无

中图分类号：

O621.2 [有机化合物性质];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of a series of N,N’-diaryl adipyl bis-azo compounds using hydrazine hydrate as reductant was investigated. The products were characterized by elemental analysis, IR and 1H NMR methods and confirmed to be N,N’-diaryl adipyl dihydrazine. The results show that hydrazine hydrate can selectively reduce azo bonds with other potential reducible bonds intact in the N,N’-diaryl adipyl bis-azo compounds. The yields are high up to 92% under mild reaction conditions. According to the previous reports, this reduction process was attributed to an indirect reduction mechanism through an intermediate diimide.

引用

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页码：872 / 876

页数：5

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