Synthesis and Crystal Structure of 9-Amino-7-(2-chlorophenyl)-6H-benzo[c]thiochromene-8,8,10(7H)-tricarbonitrile DMF Solvate

被引：0

作者：

王树良 ^{[1
]}

盛洁 ^{[1
]}

屠树江 ^{[1
]}

王香善 ^{[1
]}

机构：

[1] School of Chemistry and Chemical Engineering,Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials,Xuzhou Normal University

来源：

Chinese Journal of Structural Chemistry | 2012年 / 31卷 / 01期

关键词：

crystal structure; chromene; NMR; hydrogen bond;

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound 9-amino-7-(2-chlorophenyl)-6H-benzo[c]thiochromene-8,8,10(7H)-tricarbonitrile DMF solvate(C25H20ClN5OS,Mr = 473.97) was synthesized and crystallized.The crystal belongs to triclinic,space group P1 with a = 7.6393(2),b = 10.5212(3),c = 15.0573(4) ,α = 86.797(1),β = 79.445(1),γ = 75.379(1)°,Z = 2,V = 1151.16(5) 3,Dc = 1.367 g.cm-3,μ(MoKα) = 0.285 mm-1,F(000) = 492,R = 0.0389 and wR = 0.1005 for 3455 observed reflections(I > 2σ(I)).X-ray analysis reveals that the new six-numbered ring(C(1)-C(6)) forms a skew boat conformation.The molecule links a molecule of DMF via the N(1)-H(1A)...O(1) hydrogen bond,while another hydrogen bond C(23)-H(23A)...N(2) links adjacent molecules,forming dimmers along the a axis.

引用

下载

页码：100 / 104

页数：5

共 50 条

[1] Synthesis and Crystal Structure of 9-Amino-7-(2-chlorophenyl)-6H-benzo[c]thiochromene-8,8,10(7H)-tricarbonitrile DMF Solvate
Wang Shu-Liang
Sheng Jie
Tu Shu-Jiang
Wang Xiang-Shan
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (01) : 100 - 104
[2] PREPARATION OF 9-AMINO-9H-PURINES .2. 9-AMINO-6-CHLORO-9H-PURIN-8(7H)-ONE
TEMPLE, C
SMITH, BH
MONTGOME.JA
JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (02): : 530 - &
[3] 6-Amino-8-(2-bromophenyl)-1,7,8,8a-tetrahydro-3H-isothiochromene-5,7,7-tricarbonitrile dimethylformamide solvate
Zhang, Hai-Yan
Wu, Jian-Rong
Wang, Xiang-Shan
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2628 - U2554
[4] Synthesis and Crystal Structure of Ethyl (2-Amino-4-(2-chlorophenyl)-4H-benzo-[h]-chromene-2-yl) Formate
WANG Xiang-Shana
Chinese Journal of Structural Chemistry, 2004, (03) : 278 - 281
[5] Synthesis and crystal structure of ethyl (2-amino-4-(2-chlorophenyl)-4H-benzo-[h]-chromene-2-yl) formate
Wang, XS
Shi, DQ
Tu, SJ
Yao, CS
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (03) : 278 - 281
[6] Synthesis and Crystal Structure of 9-(2-Hydroxy-5-nitrophenyl)-9H-dibenzo[c,h]-2,7,10-trioxanthene-1,8-dione DMF Solvate
苏虹
周洁
杨科
王香善
屠树江
Chinese Journal of Structural Chemistry, 2010, 29 (05) : 779 - 783
[7] 10-amino-9-(4-chlorophenyl)-3,3,6,6-tetramethyl-3,4,5,6,9,10-hexahydroacridine-1,8(2H,7H)-dione
Tu, SJ
Zhang, JP
Zhu, XT
Xu, JN
Wang, Q
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O4082 - O4084
[8] Synthesis and Crystal Structure of 9-(2-Hydroxy-5-nitrophenyl)-9H-dibenzo[c,h]-2,7,10-trioxanthene-1,8-dione DMF Solvate
Su Hong
Zhou Jie
Yang Ke
Wang Xiang-Shan
Tu Shu-Jiang
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (05) : 779 - 783
[9] SYNTHESIS of（η5-C9H7）Ln（η8-C8H8）·2THF AND CRYSTAL STRUCTURE OF（η5-C9H7）Pr（η8-C8H8）·2THF
Ke WEN Zhong Sheng JIN Wen Qi CHEN Changchun Institute of Applied Chemistry.Academia Sinica Changchun 130022
Chinese Chemical Letters, 1991, (09) : 693 - 696
[10] Synthesis and Crystal Structure of CoCl（ieaa）(C10H7-ieai)(C10H7NH2)
FENG Yun-Long (Department of Chemistry
Chinese Journal of Structural Chemistry, 2002, (01) : 22 - 25

← 1 2 3 4 5 →