Hydrothermal Synthesis and Crystal Structure of a New One-dimensional Cobalt(Ⅱ) Complex with 2-Pyridinecarboxyic Acid and 4,4′-Bipyridine Ligands

被引：2
|
作者：
洪莉 [1 ]
李秀梅 [1 ,2 ]
王庆伟 [1 ]
牛艳玲 [2 ]
刘博 [1 ]
孙丽娟 [1 ]
机构：
[1] Jilin Normal University,Siping,Jilin , China
[2] Department of Chemistry, Tonghua Teachers College,Tonghua, Jilin ,
来源：
结构化学 | 2009年 / 28卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O621.1 [有机化学理论、物理有机化学];
学科分类号：
摘要：
A new metal-organic coordination polymer [Co(2-pya)2(4,4'-bipy)]2n·[(4,4'-bipy)0.5· H2O]2n(2-pya = 2-pyridinecarboxylic acid,4,4'-bipy = 4,4'-bipyridine) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.The complex crystallizes in tetragonal,space group I41/a with a = b = 22.719(2),c = 10.710(2) ,V = 5527.8(14) 3,C54H46N10Co2O10,Mr = 1112.87,Dc = 1.337 g/cm3,μ(MoKα) = 0.665 mm-1,F(000) = 2296,Z = 4,the final R = 0.0633 and wR = 0.1096 for 1261 observed reflections(I > 2σ(I)).It exhibits a one-dimensional chain-like structure constructed by mixed ligands of 2-pyridinedicarboxylic acid and 4,4'-bipyridine.
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页码：641 / 644
页数：4
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