Nanocomposite Membranes based on Perfl uorosulfonic Acid/Ceramic for Proton Exchange Membrane Fuel Cells

被引:0
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作者
李琼 [1 ,2 ]
WANG Guangjin [3 ]
YE Hong [4 ]
YAN Shilin [1 ]
机构
[1] School of Science, Wuhan University of Technology
[2] School of Materials Science and Engineering ,Wuhan Textile University
[3] College of Chemistry and Materials Science,Hubei Engineering University
[4] School of Transportation Engineering, Wuhan Technical College of
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中图分类号
TM911.4 [燃料电池]; TQ051.893 [];
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摘要
Perfl uorosulfonic acid/ceramic nanocomposite membranes were investigated as electrolytes for polymer electrolyte membrane fuel cell applications under low relative humidity. Different nanosized ceramics(SiO2, ZrO2, TiO2) with diameters in the range of 2-6 nm were synthesized in situ in Nafion solution through a sol-gel process and the formed nanosized ceramics were well-dispersed in the solution.The nanocomposite membranes were formed through a casting process. The nanocomposite membrane showes enhanced water retention ability and improved proton conductivity compared to those of pure Nafi on membrane. The mechanical strength of the formed nanocomposite membranes is slightly less than that of pure Nafi on membrane. The experimental results demonstrate that the polymer ceramic nanocompsite membranes are potential electrolyte for fuel cells operating at elevated temperature.
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页码:1125 / 1129
页数:5
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