Hydrothermal Synthesis and Crystal Structure of a Square Grid Coordination Copper(II) Polymer from 1,4-Bis(imidazole-1-ylmethyl)benzene

被引：7

作者：

李涛 ^{[1
]}

胡胜民 ^{[2
]}

李志华 ^{[2
]}

杜少武 ^{[2
]}

机构：

[1] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian , China,Graduate School, The Chinese Academy of Sciences, Beijing , China)

[2] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian ,

来源：

结构化学 | 2006年 / 01期

关键词：

D O I：

暂无

中图分类号：

O634 [元素有机聚合物];

学科分类号：

摘要：

The title compound [Cu(bix)2(NO3)2?H2O]n 1 (bix =1,4-bis(imidazole-1-ylme-thyl) benzene) has been synthesized by hydrothermal method. Its crystal structure is of monoclinic, space group P1 with a = 8.3075(13), b = 9.4725(13), c = 10.0192(13) ?, α = 91.088(4), β = 104.063(6), γ = 101.88(1), V = 746.5(3) ?3, Z = 1, C28H30N10O7Cu1, Mr = 682.16, Dc = 1.518 g/cm3, μ = 0.796 mm─1, F(000) = 353, the final R = 0.0535 and wR = 0.0996 for 2921 observed reflections with I > 2σ(I). Each bix ligand binds two Cu(II) ions to form a 2-D(4,4) square grid layer, which is connected by hydrogen bonds showing large channels occupied by solvated water molecules and nitrate anions.

引用

页码：85 / 89

页数：5

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