An Interpenetrated Three-dimensional Framework Sodium Lanthanide Carboxylate Based on[Ho4（μ3-OH）4]8+ Cluster

被引：1
|
作者：
胡冰 [1 ,2 ]
黄小荥 [1 ]
机构：
[1] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
[2] Graduate School of Chinese Academy of Sciences
来源：
结构化学 | 2011年 / 30卷 / 02期
关键词：
lanthanide; carboxylate; high-nuclear cluster; crystal structure;
D O I：
暂无
中图分类号：
O611.3 [性质];
学科分类号：
070301 ; 081704 ;
摘要：
A novel sodium holmium carboxylate compound,namely Na 4 Ho 4 (μ 3-OH) 4 (1,4BDC) 6 ·6.25H 2 O (1,1,4-BDC=1,4-benzenedicarboxylate),has been solvothermally synthesized and structurally characterized.The structure features a two-fold interpenetrated three-dimensional open-framework constructed by the [Ho 4 (μ 3-OH) 4 ] 8+ clusters bridged by 1,4-BDC ligands.The Na + ions and lattice water molecules are located in the channels.The structure is further stabilized by hydrogen-bonding and π-π stacking interactions.The thermal stability of the compound has been investigated via thermogravimetric analysis.
引用
收藏
页码：240 / 246
页数：7
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