Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamides

被引:0
|
作者
Sen Qiao [1 ]
Kunquan Chen [1 ]
Qiang Liu [1 ]
Zhixiang Wang [1 ,2 ]
Xiangyu Chen [1 ,2 ]
机构
[1] School of Chemical Sciences, University of the Chinese Academy of Sciences
[2] Binzhou Institute of Technology, Weiqiao-UCAS Science and Technology Park
基金
中国国家自然科学基金; 中央高校基本科研业务费专项资金资助;
关键词
D O I
暂无
中图分类号
O644.1 [光化学]; O643.36 [催化剂];
学科分类号
070304 ; 081704 ; 081705 ;
摘要
A charge transfer complex(CTC)-enabled photoreduction of ether phosphonium salts for the generation of oxyalkyl radicals was described. The photoreduction provides a convenient method to achieve selective oxyalkylation of enamides with broad substrate scope. The method features operational simplicity, mild and inherent green conditions.
引用
收藏
页码:439 / 442
页数:4
相关论文
共 50 条
  • [21] Supramolecular Complex Surfactants and Structured Liquids Enabled by Cation-π and Charge-Transfer Interactions
    Luo, Jiaqiu
    Sun, Shuyi
    Xia, Zhiqin
    Wen, Yunhui
    Feng, Weixiao
    Shi, Shaowei
    LANGMUIR, 2024, 40 (33) : 17747 - 17752
  • [22] Spectroscopic observation of charge transfer complex formation of persistent perfluoroalkyl radical with aromatics, olefin, and ether
    Ono, Taizo
    Ohta, Kazutoku
    JOURNAL OF FLUORINE CHEMISTRY, 2014, 167 : 198 - 202
  • [23] The Mechanism of the Initial Dark Oxidation of Ethers and the Ether-Oxygen Contact Charge Transfer Complex
    Jun Min ZHU
    Wei Xiao CAO and Xin De FENG(College of Chemistry and Molecular Engineering
    Chinese Chemical Letters, 1997, (10) : 869 - 872
  • [24] The mechanism of the initial dark oxidation of ethers and the ether-oxygen contact charge transfer complex
    Zhu, JM
    Cao, WX
    Feng, XD
    CHINESE CHEMICAL LETTERS, 1997, 8 (10) : 869 - 872
  • [25] δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer
    Hu, Anhua
    Guo, Jing-Jing
    Pan, Hui
    Tang, Haoming
    Gao, Zhaobo
    Zuo, Zhiwei
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (05) : 1612 - 1616
  • [26] Synthesis and physical properties of TCNQ charge - Transfer salts of amine copper or nickel complex cations
    Xie, B
    Li, JS
    Men, ZY
    ACTA CHIMICA SINICA, 1998, 56 (03) : 263 - 269
  • [27] SEMICONDUCTING BEHAVIOR IN SIMPLE AND COMPLEX CHARGE-TRANSFER SALTS OF TETRACYANOQUINODIMETHANE WITH SUBSTITUTED PYRIDINIUM DONORS
    LANE, JE
    FICO, TR
    LOMBARDO, A
    BLAKEMORE, JS
    JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (09): : 3981 - 3986
  • [28] The reaction of iodine with 9-methylacridine: formation of polyiodide salts and a charge-transfer complex
    Rimmer, EL
    Bailey, RD
    Pennington, WT
    Hanks, TW
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (11): : 2557 - 2562
  • [29] Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation
    Christopher K. Hill
    John F. Hartwig
    Nature Chemistry, 2017, 9 : 1213 - 1221
  • [30] Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation
    Hill, Christopher K.
    Hartwig, John F.
    NATURE CHEMISTRY, 2017, 9 (12) : 1213 - 1221