GENERAL-SYNTHESIS OF METHYL-CYCLOBUTANES AND DIMETHYL-CYCLOBUTANES FROM SIMPLE 1,3-DIOLS BY PHASE-TRANSFER CATALYSIS

被引：9

作者：

TOROK, B

MOLNAR, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 07期

关键词：

D O I：

10.1039/p19930000801

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general method is described for the preparation of methyl- and dimethyl-cyclobutanes from simple 1,3-diols. The key steps of the procedure are a phase transfer catalysed ring closure and the transformation of a carboxyl group to a methyl group. Phase transfer catalysis provides good yields in the synthesis of the cyclobutane skeleton.

引用

页码：801 / 804

页数：4

共 33 条

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[27] MECHANISM OF FORMATION OF 3-METHYL DERIVATIVES OF IMIDAZO[2,1-b]THIAZOLES AND THEIR BENZO ANALOGS IN THE REACTIONS OF 2-MERCAPTOIMIDAZOLE AND 2-MERCAPTOBENZIMIDAZOLE WITH 1,3-DICHLOROACETONE UNDER PHASE-TRANSFER CATALYSIS CONDITIONS
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[30] Regio- and stereoselective synthesis of (Z)-(2,3-dihydro-1,4-thiaselenin-2-yl) vinyl sulfides from 2-bromomethyl-1,3-thiaselenole under phase-transfer catalysis conditions
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