GENERAL-SYNTHESIS OF METHYL-CYCLOBUTANES AND DIMETHYL-CYCLOBUTANES FROM SIMPLE 1,3-DIOLS BY PHASE-TRANSFER CATALYSIS

被引：9

作者：

TOROK, B

MOLNAR, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 07期

关键词：

D O I：

10.1039/p19930000801

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general method is described for the preparation of methyl- and dimethyl-cyclobutanes from simple 1,3-diols. The key steps of the procedure are a phase transfer catalysed ring closure and the transformation of a carboxyl group to a methyl group. Phase transfer catalysis provides good yields in the synthesis of the cyclobutane skeleton.

引用

页码：801 / 804

页数：4

共 33 条

[1] Synthesis of Pyrazoles from 1,3-Diols via Hydrogen Transfer Catalysis
Schmitt, Daniel C.
Taylor, Alexandria P.
Flick, Andrew C.
Kyne, Robert E., Jr.
ORGANIC LETTERS, 2015, 17 (06) : 1405 - 1408
[2] CONVENIENT GENERAL SYNTHESIS OF 3-ALKYL-1,3-DIARYLTRIAZENES FROM 1,3-DIARYLTRIAZENES USING PHASE-TRANSFER CATALYSIS
VERNIN, G
METZGER, J
SYNTHESIS-STUTTGART, 1978, (12): : 921 - 924
[3] NEW SIMPLE CATALYST FOR SYNTHESIS OF 1,3-DIOLS AND THEIR MONOESTERS FROM LINEAR ALIPHATIC-ALDEHYDES
POCHINI, A
SALERNO, G
UNGARO, R
SYNTHESIS-STUTTGART, 1975, (03): : 164 - 165
[4] A simple entry into 1,3-diols from (R)-2,3-cyclohexylideneglyceraldehyde: synthesis of (-)-galantinic acid
Dhotare, Bhaskar
Chattopadhyay, Angshuman
TETRAHEDRON-ASYMMETRY, 2009, 20 (17) : 2007 - 2013
[5] A FACILE SYNTHESIS OF 1,3-DIALKYL-5-FLUOROURACILS BY MEANS OF PHASE-TRANSFER CATALYSIS
HOSHIKO, T
WATANABE, Y
OZAKI, S
HETEROCYCLES, 1983, 20 (12) : 2429 - 2431
[6] POLYMERIZATION BY PHASE-TRANSFER CATALYSIS .8. SYNTHESIS AND CHARACTERIZATION OF POLYTHIOCARBONATES FROM DIPHENOLS WITH METHYL-GROUPS
TAGLE, LH
DIAZ, FR
SALAS, P
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1989, A26 (09): : 1321 - 1334
[7] ORGANOBORANES .36. A SIMPLE, GENERAL-SYNTHESIS OF ALKYNYL KETONES AND [E]-1,3-ALKENYNES VIA THEXYLCHLOROBORANE-DIMETHYL SULFIDE
BROWN, HC
BHAT, NG
BASAVAIAH, D
ISRAEL JOURNAL OF CHEMISTRY, 1984, 24 (02) : 72 - 75
[8] One-Step Green Synthesis of Isoeugenol Methyl Ether from Eugenol by Dimethyl Carbonate and Phase-Transfer Catalysts
Zhang, Zhihai
Gong, Yin
Xue, Xinru
Hu, Mengshuang
Zhou, Min
Zhao, Yao
Hu, Zhiqiang
MOLECULES, 2024, 29 (02):
[9] SYNTHESIS OF BENZOFURANS BY PHASE-TRANSFER CATALYSIS - INTRAMOLECULAR CYCLIZATION OF ALPHA-ARYL-SUBSTITUTED 1,3-DICARBONYL COMPOUNDS
DAVYDOV, DV
BELETSKAYA, IP
RUSSIAN CHEMICAL BULLETIN, 1995, 44 (07) : 1344 - 1345
[10] SYNTHESIS OF 1-ALKYL AND 1,3-DIALKYL-2-BENZIMIDAZOLONES FROM 1-ALKENYL-2-BENZIMIDAZOLONES USING PHASE-TRANSFER CATALYSIS TECHNIQUE
VERNIN, G
DOMLOG, H
SIV, C
METZGER, J
ELSHAFEI, AK
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1981, 18 (01) : 85 - 89

← 1 2 3 4 →