KINETICS AND MECHANISM OF PD(II) CATALYZED OXIDATION OF SOME PRIMARY AMINES AND AMINOALCOHOLS BY ALKALINE HEXACYANOFERRATE(III)

被引：0

作者：

SHUKLA, A ^{[1
]}

UPADHYAY, SK ^{[1
]}

机构：

[1] HARCOURT BUTLER TECHNOL INST,DEPT CHEM,KANPUR 208002,UTTAR PRADESH,INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1995年 / 34卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of primary amines (n-butylamine and isopropylamine) and aminoalcohols (2-aminoethanol and 3-aminopropanol) by alkaline hexacyanoferrate(III) have been studied in the presence of PdCl2 as catalyst. The order of reaction in Fe(CN)6(3-) is always unity while that in substrate decreases from unity at higher [substrate]. The rate is proportional to [Pd(II)] and is independent to [OH-] (under the conditions when [OH-]much-greater-than [PdCl2]). A mechanism involving {Pd(II)-A} and {Pd(II)-(A)2} (where A represents amine or aminoalcohol) intermediate complexes is proposed.

引用

页码：120 / 123

页数：4

共 50 条

[31] KINETICS AND MECHANISM OF OS(VIII) CATALYZED OXIDATION OF CINNAMATE ION BY ALKALINE POTASSIUM HEXACYANOFERRATE (III)
KUMAR, S
MATHUR, PC
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1979, 41 (04): : 599 - 602
[32] KINETICS AND MECHANISM OF RU(VIII) CATALYZED OXIDATION OF DULCITOL AND XYLITOL BY HEXACYANOFERRATE(III) IN ALKALINE MEDIA
SINGH, MP
KOTHARI, S
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1983, 22 (08): : 697 - 698
[33] MECHANISM OF RUTHENIUM(III) CATALYZED OXIDATION OF SOME ALCOHOLS BY HEXACYANOFERRATE(III) IN MILD ALKALINE-MEDIUM
SINGH, MP
TANDON, PK
MEHROTRA, A
GUPTA, A
SINGH, R
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1990, 29 (06): : 590 - 591
[34] Kinetics and mechanism of Cu(II) catalyzed oxidation of hexacyanoferrate(III) with peroxodiphosphate in acetate buffers
Jha, S
Jha, KK
Mishra, DK
OXIDATION COMMUNICATIONS, 1996, 19 (01): : 125 - 134
[35] IRIDIUM(III) CHLORIDE CATALYZED OXIDATION OF SOME ALCOHOLS BY ALKALINE HEXACYANOFERRATE(III)
SINGH, MP
TANDON, PK
SINGH, RM
MEHROTRA, A
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1990, 67 (06) : 458 - 462
[36] Kinetics and mechanism of uncatalyzed and ruthenium(III)-catalyzed oxidation of formamidine derivative by hexacyanoferrate(III) in aqueous alkaline medium
Fawzy, Ahmed
JOURNAL OF CHEMICAL SCIENCES, 2016, 128 (05) : 733 - 743
[37] Kinetics and mechanism of the ruthernium(III) catalyzed oxidation of propane-1,3-diol by alkaline hexacyanoferrate(III)
A. E. Mucientes
F. J. Poblete
F. Santiago
J. Casado
Reaction Kinetics and Catalysis Letters, 1997, 62 : 293 - 297
[38] KINETICS AND MECHANISM OF OXIDATION OF ALIPHATIC-ALCOHOLS AND DIOLS BY ALKALINE HEXACYANOFERRATE(III) CATALYZED BY RU(III) CHLORIDE
RADHAKRISHNAMURTI, PS
SAHU, B
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1979, 17 (01): : 95 - 97
[39] Base-catalyzed oxidation: Kinetics and mechanism of hexacyanoferrate (III) oxidation of methyl cellulose polysaccharide in alkaline solutions
Hassan, R. M.
Ibrahim, S. M.
Zaafarany, I. A.
Fawzy, A.
Takagi, H. D.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2011, 344 (1-2) : 93 - 98
[40] Kinetics and mechanism of ruthenium(III) catalyzed oxidation of ethane-1,2-diol by alkaline hexacyanoferrate(III)
Mucientes, AE
Poblete, FJ
Santiago, F
Rodriguez, MA
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1997, 94 (09) : 1642 - 1658

← 1 2 3 4 5 →