EQUILIBRIUM BETWEEN DIAMAGNETISM AND PARAMAGNETISM IN A MAGNETIC-FIELD

被引：2

作者：

JANSEN, AGM ^{[1
]}

LEJAY, J ^{[1
]}

WIEGELMANN, H ^{[1
]}

WYDER, P ^{[1
]}

BRONGER, W ^{[1
]}

机构：

[1] TECH HSCH AACHEN,INST ANORGAN CHEM,D-52062 AACHEN,GERMANY

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1993年 / 182卷

关键词：

MAGNETIC FIELD EFFECTS; SPIN EQUILIBRIA; HIGH-SPIN LOW-SPIN TRANSITIONS;

D O I：

10.1524/zpch.1993.182.Part_1_2.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For a Co complex in an optical transmission experiment and for a Fe complex by means of a dilatometer, the spin crossover between a paramagnetic high-spin state and a diamagnetic low-spin state has been observed to shift to the paramagnetic side in magnetic fields up to 20 T. In a thermodynamic analysis, the quadratic dependence of the shift in the spin transition can be evaluated quantitatively.

引用

页码：1 / 8

页数：8

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