SYNTHESIS OF 4-O-MONOACRYLOYL AND 6-O-MONOACRYLOYL DERIVATIVES OF SUCROSE BY SELECTIVE HYDROLYSIS OF 4,6-O-(1-ETHOXY-2-PROPENYLIDENE)SUCROSE - POLYMERIZATION AND COPOLYMERIZATION WITH STYRENE

被引：15

作者：

FANTON, E

FAYET, C

GELAS, J

DEFFIEUX, A

FONTANILLE, M

JHURRY, D

机构：

[1] ECOLE NATL SUPER CHIM CLERMONT FERRAND,ENSEMBLE SCI CEZEAUX,BP 187,F-63174 CLERMONT FERRAND,FRANCE

[2] INST PIN,CHIM POLYMERES ORGAN LAB,F-33405 TALENCE,FRANCE

来源：

CARBOHYDRATE RESEARCH | 1993年 / 240卷

关键词：

Acrylic monomers - Biodegradation - Copolymerization - Derivatives - Esters - Hydrolysis - Polymerization - Styrene - Synthesis (chemical) - Vinyl resins;

D O I：

10.1016/0008-6215(93)84179-A

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of an ethylenic orthoester of sucrose by transorthoesterification of an acrylic reagent with sucrose is described. Mild hydrolysis of this orthoester gave sucrose selectively monosubstituted by an acryloyl group at either the 4-O- or the 6-O-position. These acrylates were homopolymerized and copolymerized with styrene, and the corresponding polymers were characterized.

引用

页码：143 / 152

页数：10

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