Protonation of an eta(6)-arene-metal complex to yield a metal-hydrogen bond via an electrophilic aromatic substitution mechanism

被引：22

作者：

Kowalski, AS ^{[1
]}

Ashby, MT ^{[1
]}

机构：

[1] UNIV OKLAHOMA,DEPT CHEM & BIOCHEM,NORMAN,OK 73019

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1995年 / 117卷 / 50期

关键词：

D O I：

10.1021/ja00155a030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：12639 / 12640

页数：2

共 48 条

[41] STEREO-SPECIFIC AND REGIO-SPECIFIC C-C BOND FORMATION VIA THE COUPLING OF ELECTROPHILIC AND NUCLEOPHILIC ORGANOTRANSITION-METAL COMPLEXES - THE X-RAY CRYSTAL-STRUCTURE OF [RU(CO)2(PPH3)(ETA-2,ETA-3-C8H8R)][PF6].0.5CH2CL2(R=CH2C(ME)=CH2)
CONNELLY, NG
ORPEN, AG
QUARMBY, IC
SHERIDAN, JB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 299 (03) : C51 - C55
[42] ELECTROPHILIC CLEAVAGE OF THE ALKYL-METAL BOND IN THE COMPLEXES, CP-STAR-OS(CO)LR(CP-STAR=ETA-5-C5ME5, L= CO, PME2PH, R= ME, ET, I-PR, CH2PH) - EVIDENCE FOR THE FORMATION OF INTERMEDIATES VIA OXIDATIVE ADDITION OF THE ELECTROPHILE TO THE OSMIUM
JOHNSTON, LJ
BAIRD, MC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 444 - INOR
[43] INFLUENCE ON TRANSITION-METAL ARENE COMPLEX-FORMATION OF HYDROGENATION AND REARRANGEMENT OF POLYAROMATIC SUBSTRATES INDUCED BY ALUMINUM TRICHLORIDE - OCTAHYDROPHENANTHRENE COMPLEXES FROM TETRALIN - X-RAY CRYSTAL-STRUCTURE OF ETA-5-1,2,3,4,5,6,7,8,9,-ENDO-NONAHYDRO-9-EXO-METHYLPHENANTHRENYL(TRICARBONYL)-MANGANESE
STOBART, SR
ZAWOROTKO, MJ
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (24) : 1700 - 1702
[44] CARBON HYDROGEN AND METAL-CARBON BOND FORMATION AND BREAKAGE IN THERMAL-REACTIONS OF BIS(MESITYL)(CYCLO-OCTATETRAENE)ZIRCONIUM(IV) DERIVATIVES - CRYSTAL-STRUCTURES OF [ZR(ETA-8-C8H8)(MES)2], [(ZR(ETA-8-C8H8)[ETA-OC(MES)2])2], [(ZR(ETA-8-C8H8)-(MU-2,4-ME2-6-CH2C6H2))2], AND [(ZR(ETA-8-C8H8))2(MU-MES)(MU-2,4-ME2-6-CHC6H2)] (MES = 2,4,6-ME3C6H2)
BERNO, P
STELLA, S
FLORIANI, C
CHIESIVILLA, A
GUASTINI, C
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (09): : 2669 - 2677
[45] ARSENIC SULFUR HETEROCYCLE FORMATION VIA METAL COORDINATION - SYNTHESIS AND MOLECULAR-STRUCTURE OF CYCLO-(CH3ASS)3, CYCLO-(CH3ASS)4, [(CO)3MO][ETA-3-CYCLO-(CH3AS)6S3], AND THE TRIPLE-DECKER SANDWICH COMPLEX [ETA-5-(C5H5)2MO2(ETA-2,MU-AS3)(ETA-2,MU-ASS)]
DIMAIO, AJ
RHEINGOLD, AL
INORGANIC CHEMISTRY, 1990, 29 (04) : 798 - 804
[46] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .15. CARBON CARBON AND CARBON HYDROGEN-BOND ACTIVATION IN THE REACTIONS BETWEEN ETHYLENE AND DITUNGSTEN HEXAALKOXIDES - W2(OCH2-TERT-BU)6(ETA-2-C2H4)2, W2(OR)6(CH2)4(ETA-2-C2H4), AND W2(OR)6(MU-CCH2CH2CH2) (WHERE R = CH2-TERT-BU, ISO-PR, CYCLO-C5H9, AND CYCLO-C6H11) - PREPARATIONS, PROPERTIES, STRUCTURES, AND REACTION-MECHANISMS
CHISHOLM, MH
HUFFMAN, JC
HAMPDENSMITH, MJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) : 5284 - 5299
[47] AN UNUSUAL EFFECT OF LIGAND METHYL-SUBSTITUTION IN THE REACTION OF TRICARBONYL (GROUP-6A METAL) [HYDROTRIS(3,5-R2-1-PYRAZOLYL)BORATO] ANIONS (R=H, ME) WITH ARENEDIAZONIUM CATIONS - X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF A MOII ETA-2-AROYL COMPLEX, (MO(ETA-2-COC6H4ME-PARA) (CO)2(HB(3,5-ME2C3HN2)3)) AND OF AN ETA-2-HEXAHYDROBENZOYL ANALOG, [MO(ETA-2-COC6H11) (CO)2(HB(3,5-ME2C3HN2)3)]IO
DESMOND, T
LALOR, FJ
FERGUSON, G
RUHL, B
PARVEZ, M
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (01) : 55 - 56
[48] PHOTOCHEMICAL HYDROGENOLYSIS OF THE PHOSPHORUS-CYCLOPENTADIENYL BOND OF (CO)4MNMO(CO)3[ETA-5-C5H4P(C6H4-P-CH3)2] AND FORMATION OF THE PHOSPHIDO-BRIDGED METAL HYDRIDE COMPLEX (CO)4MN[MU-P(C6H4-PARA-CH3)2](MU-H)MO(CO)2(C5H5)
CASEY, CP
BULLOCK, RM
ORGANOMETALLICS, 1984, 3 (07) : 1100 - 1104

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