SYNTHETIC STUDIES ON AROMADENDRANE-TYPE COMPOUNDS .2. STEREOSELECTIVE SYNTHESIS OF (+)-1,2-DIDEHYDROAROMADENDRANE

被引：0

作者：

TANAKA, T ^{[1
]}

FUNAKOSHI, Y ^{[1
]}

UENAKA, K ^{[1
]}

MAEDA, K ^{[1
]}

MIKAMIYAMA, H ^{[1
]}

IWATA, C ^{[1
]}

机构：

[1] OSAKA UNIV, FAC PHARMACEUT SCI, SUITA, OSAKA 565, JAPAN

来源：

CHEMICAL & PHARMACEUTICAL BULLETIN | 1994年 / 42卷 / 06期

关键词：

AROMADENDRANE; (+)-1,2-DIDEHYDROAROMADENDRANE; STEREOSELECTIVE SYNTHESIS; STEREOSPECIFIC METHYLATION; TRICYCLO[6.3.0.0(2,4)]UNDECANE; REDUCTIVE DEOXYGENATION;

D O I：

暂无

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The reactivity of the tricyclic enone, (+)-(1S,2R,4R,7R)-3,3,7-trimethyltricyclo[6.3.0.0(2,4)]undec-8-en-10-one (1), obtained previously as the key intermediate for the synthesis of compounds bearing the aromadendrane nucleus was investigated, and a natural aromadendrane-type sesquiterpene, (+)-1,2-didehydroaromadendrane (2), was synthesized via regio- and stereo-specific introduction of a methyl group at the C-11 position of 1 followed by reductive deoxygenation.

引用

页码：1243 / 1246

页数：4

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