RADICAL CYCLIZATION OF EPOXYKETONES VIA A 1,5BU(N)3SN GROUP OR A 1,5-H ATOM TRANSFER

被引：43
|
作者：
KIM, S
KOH, JS
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期
关键词：
D O I：
10.1039/c39920001377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Radical cyclization of epoxyketones is initiated by Bu(n)3Sn radical addition to epoxyketones, followed by epoxide fragmentation, 1,5-H- or 1,5-Bu(n)Sn3 transfer, and cyclization.
引用
收藏
页码：1377 / 1378
页数：2
相关论文
共 50 条
  • [41] [1,5-Bis(1-methyl-1H-imidazol-2-yl-methyl-κN3)-1,5-diazacyclooctane-N,N′ ]chlorocobalt(II) perchlorate
    Du, M
    Shang, ZL
    Xu, Q
    Zhang, RH
    Leng, XB
    Bu, XH
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 (07) : 769 - 770
  • [42] Cascade [1,5]-Hydride Transfer/Cyclization for Synthesis of [3,4]-Fused Oxindoles
    Zhu, Shuai
    Chen, Chunqi
    Duan, Kang
    Sun, Yun-Ming
    Li, Shuai-Shuai
    Liu, Qing
    Xiao, Jian
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (13): : 8440 - 8448
  • [43] Efficient construction of tetrahydroquinolines via fluorinated alcohol mediated cascade [1,5]-hydride transfer/cyclization
    Chen, Chunqi
    Xu, Lubin
    Wang, Liang
    Li, Shuai-Shuai
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (39) : 7109 - 7114
  • [44] RADICAL CATION CYCLIZATION OF 1,5-HEXADIENE TO CYCLOHEXENE VIA THE CYCLOHEXANE-2,5-DIYL RADICAL CATION INTERMEDIATE
    GUO, QX
    QIN, XZ
    WANG, JT
    WILLIAMS, F
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (06) : 1974 - 1976
  • [45] Transition-metal-free radical relay cyclization of vinyl azides with 1,4-dihydropyridines involving a 1,5-hydrogen-atom transfer: access to α-tetralone scaffolds
    Liao, Yangzhen
    Ran, Yu
    Liu, Guijun
    Liu, Peijun
    Liu, Xiaozu
    ORGANIC CHEMISTRY FRONTIERS, 2020, 7 (22) : 3638 - 3647
  • [46] Recent Advances on Alkoxy Radicals-Mediated C(sp3)-H Bond Functionalization via 1,5-Hydrogen Atom Transfer
    Zhu Yanshuo
    Wang Hongyan
    Su Penghua
    Zhang Ke'na
    Wang Qilin
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2024, 44 (01) : 1 - 17
  • [47] Free-radical functionalisation of β-amino alcohols via 1,5-hydrogen atom abstraction in 1,3-oxazolidines
    Gosain, R
    Norrish, AM
    Wood, ME
    TETRAHEDRON LETTERS, 1999, 40 (36) : 6673 - 6676
  • [48] Radical rearrangements of alpha-Iodoalkyl phenyl sulfones involving 1,5 hydrogen atom transfer reactions
    Masnyk, M
    TETRAHEDRON LETTERS, 1997, 38 (05) : 879 - 882
  • [49] Generation of 4′-Carbon Radicals via 1,5-Hydrogen Atom Transfer for the Synthesis of Bridged Nucleosides
    Ito, Yuta
    Mizuno, Koichi
    Sumise, Sanae
    Kimura, Airi
    Noguchi, Nozomi
    Fuchi, Yasufumi
    Hari, Yoshiyuki
    ORGANIC LETTERS, 2022, 24 (41) : 7696 - 7700
  • [50] Selective N-α-C-H alkylation of cyclic tertiary amides via visible-light-mediated 1,5-hydrogen atom transfer
    Wang, Junlei
    Xie, Qinglin
    Gao, Guocheng
    Li, Hongqing
    Lu, Wenyun
    Cai, Xiaodong
    Chen, Xuemei
    Huang, Binbin
    ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (17) : 4394 - 4399
12345