Absolute rate constants for the quenching of O-2 (b(1)Sigma(+)(g)) by unsaturated hydrocarbons

被引：7

作者：

Stuhl, F. ^{[1
]}

Niki, H. ^{[1
]}

机构：

[1] Ford Motor Co, Sci Res Staff, Dearborn, MI 48121 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 5卷 / 09期

关键词：

D O I：

10.1016/0009-2614(70)85050-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Absolute rate constants for the quenching of metastable O-2(b(1)Sigma(+)(g)) by acetylene. ethylene. propylene. butene- 1, trans-butene-2, cis-butene-2, and tetramethylethylene were determined at 300%. The rate constants range from 4 to 10 x 10(-13) cm(3)molecule(-1)sec(-1), and exhibit a systematic variation with molecular structure of the olefins.

引用

页码：573 / 575

页数：3

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