NAD(P)+-NAD(P)H MODELS .85. THE ENZYME/COENZYME/METAL/SUBSTRATE QUATERNARY COMPLEX GENERATED IN THE TRANSITION-STATE OF THE REDUCTION OF BENZOYLFORMATE WITH NAD(P)H MODELS

被引：3

作者：

MIKATA, Y ^{[1
]}

MIZUKAMI, K ^{[1
]}

IKEHARA, K ^{[1
]}

机构：

[1] KYOTO UNIV,INST CHEM RES,UJI,KYOTO 611,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 36期

关键词：

D O I：

10.1016/0040-4039(95)01298-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselectivities in the reduction of methyl benzoylformate with NAD(P)H model compounds, N-alpha-methylbenzyl-1-propyl-1,4-dihydronicotinamide (PNPH) and N-benzyl-1-propyl-1,4-dihydronicotinamide (PNBH), in the presence of N-protected amino acids have been studied. The stereoselectivity was perturbed by the amino acids which have a side chain capable of coordinating onto Mg2+.

引用

页码：6491 / 6494

页数：4

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