REACTION OF THE FLUORIDE ANION WITH ACETONITRILE, CHLOROFORM AND METHYLENE-CHLORIDE

被引：88
|
作者：
CHRISTE, KO
WILSON, WW
机构：
[1] Rocketdyne, a Division of Rockwell International Corporation, Canoga Park
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 47卷 / 01期
关键词：
D O I：
10.1016/S0022-1139(00)80453-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
19F and 1H NMR spectra of the F- anion in CH3CN and CD3CN solutions show that the F- anion can abstract a proton from CH3CN resulting in the slow formation of the bifluoride and acetonitrile anions. With chloroform or methylene chloride the F- anion undergoes halogen exchange reactions at room temperature. These reactions demonstrate the exceptional reactivity of the free fluoride anion when present as a highly soluble salt. © 1990.
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页码：117 / 120
页数：4
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