BINARY-SYSTEMS WITH LI2SO4 AS ONE OF THE COMPONENTS

被引:8
|
作者
TOUBOUL, M
LESAMEDI, E
SEPHAR, N
BROSZNIOWSKI, F
EDERN, P
BETOURNE, E
机构
[1] Laboratoire de Réactivité et de Chimie Des Solides, URA CNRS 1211, Université De Picardie, Amiens, Cedex, 80039
来源
JOURNAL OF THERMAL ANALYSIS | 1993年 / 40卷 / 03期
关键词
BINARY SYSTEMS; DTA; LI2SO4; SOLID SOLUTION; XRD;
D O I
10.1007/BF02546877
中图分类号
O414.1 [热力学];
学科分类号
摘要
Six binary systems were studied using DTA with supplementary XRD. In Li2SO4-MSO4 SYStems (M = Mg, Co, Ni), a primary solid solution with alpha-Li2SO4 StruCtUre (high-temperature form) and an incongruent melting compound Li2My(SO4)1+y exist: y = 2 with Mg and y = 1 with Co and Ni. In Li2SO4-Li3XO4 systems (X = P, V), which are very different from one another, only primary solid solutions exist. In the Li2SO4-Li2B4O7 system there is neither a solid solution nor an intermediate compound. Comparisons with previous investigations are made.
引用
收藏
页码:1151 / 1156
页数:6
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