SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE MIXED LITHIUM MAGNESIUM AMIDE, [(PHCH2(ME2NCH2CH2)N)4LI2MG] - A NEW-TYPE OF MAGNESIATE COMPLEX FREE OF A DONOR SOLVENT AS LIGAND

被引：16
|
作者：
CLEGG, W
HENDERSON, KW
MULVEY, RE
ONEIL, PA
机构：
[1] UNIV STRATHCLYDE, DEPT PURE & APPL CHEM, GLASGOW G1 1XL, SCOTLAND
[2] UNIV NEWCASTLE UPON TYNE, DEPT CHEM, NEWCASTLE UPON TYNE NE1 7RU, TYNE & WEAR, ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期
关键词：
D O I：
10.1039/c39930000969
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.
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页码：969 / 970
页数：2
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