HETEROGENEOUS-HOMOGENEOUS RADICAL REACTIONS IN THE PROCESSES OF DEEP CATALYTIC-OXIDATION

被引：0
|
作者：
ISMAGILOV, ZP [1 ]
PAK, SN [1 ]
ERMOLAEV, VK [1 ]
机构：
[1] ACAD SCI USSR,INST CATALYSIS RES,NOVOSIBIRSK,USSR
来源：
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1991年 / 27卷 / 05期
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D O I：
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Using the matrix isolation ESR technique the conditions for the initiation of a heterogeneous-homogeneous reaction by total oxidation catalysts CuCr2O4/gamma-Al2O3 and Pt/gamma-Al2O3 and reaction regularities at atmospheric pressure have been studied. The dependences of contribution of homogeneous reactions into the total conversion in the presence of a catalyst on temperature and reactants ratio and concentrations have been established.
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页码：548 / 553
页数：6
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