RATE CONSTANTS FOR HYDROGEN ABSTRACTION REACTIONS OF NO3 IN AQUEOUS-SOLUTION

被引：23
|
作者：
SHASTRI, LV
HUIE, RE
机构：
[1] Chemical Kinetics Division, National Institute of Standards and Technology, Gaithersburg, Maryland
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1990年 / 22卷 / 05期
关键词：
D O I：
10.1002/kin.550220507
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Rate constants have been measured by pulse radiolysis for the reactions of the NO3 radical with five cyclic ethers and a series of alcohols. Rate constants ranged from 3.5 × 104 M×1 s×1 for deuterated methanol to 1.1 × 107 M−1 s−1 for tetrahydrofuran. The rate constants for the reactions of NO3 with the alcohols 1‐propanol to 1‐heptanol were found to be linearly dependent on the number of CH3 groups with a group reactivity of 6.4 × 105 M−1 s−1. Copyright © 1990 John Wiley & Sons, Inc.
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页码：505 / 512
页数：8
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