REACTIONS OF 1,3-BUTANEDIOL WITH HEXACHLOROCYCLOTRIPHOSPHAZENE - UNUSUAL NON-EQUIVALENCE OF PHOSPHORUS NUCLEI IN THE SPIROCYCLIC PRODUCT N3P3CL4[OCH(CH3)CH2CH2]

被引：13

作者：

MURALIDHARA, MG ^{[1
]}

GROVER, N ^{[1
]}

CHANDRASEKHAR, V ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

POLYHEDRON | 1993年 / 12卷 / 12期

关键词：

D O I：

10.1016/S0277-5387(00)84591-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of hexachlorocyclotriphosphazene, N3P3Cl6 (1), with 1,3-butane-diol affords the tetrachloro derivative N3P3Cl4[OCH(CH3)(CH2)2O] (2). This product (2) and its derivative N3P3(NMe2)4[OCH(CH3)(CH2)2O] (3) possess spirocyclic structures. The phosphorus NMR spectrum of 2 is of the AMX type instead of the expected AB2 or AX2 types observed for other spirocyclic products. The synthesis of 2 and 3 and their characterization by proton and phosphorus NMR are discussed.

引用

页码：1509 / 1513

页数：5

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