SYNTHESIS AND CHARACTERIZATION OF THE ENCAPSULATED STANNOCENES [(C3H7)(3)C5H2]SN2 AND [(C3H7)(4)C5H]SN2

被引：26
|
作者：
BURKEY, DJ
HANUSA, TP
机构：
[1] Department of Chemistry, Vanderbilt University, Nashville
来源：
ORGANOMETALLICS | 1995年 / 14卷 / 01期
关键词：
D O I：
10.1021/om00001a005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The encapsulated stannocenes [(C3H7)(4)C5H]Sn-2 and [(C3H7)(3)C5H2]Sn-2 are isolated as an, air-stable, high-melting solid and an air-sensitive oil, respectively; their physical properties mirror those of alkaline-earth metallocenes containing these ligands. The X-ray crystal structure of [(C3H7)(4)C5H]Sn-2 reveals a bent-metallocene geometry closely related to that of [(C3H7)(4)C5H]Ca-2
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页码：11 / 13
页数：3
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