SYNTHESIS AND CHARACTERIZATION OF THE ENCAPSULATED STANNOCENES [(C3H7)(3)C5H2]SN2 AND [(C3H7)(4)C5H]SN2

被引：26

作者：

BURKEY, DJ

HANUSA, TP

机构：

[1] Department of Chemistry, Vanderbilt University, Nashville

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 01期

关键词：

D O I：

10.1021/om00001a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The encapsulated stannocenes [(C3H7)(4)C5H]Sn-2 and [(C3H7)(3)C5H2]Sn-2 are isolated as an, air-stable, high-melting solid and an air-sensitive oil, respectively; their physical properties mirror those of alkaline-earth metallocenes containing these ligands. The X-ray crystal structure of [(C3H7)(4)C5H]Sn-2 reveals a bent-metallocene geometry closely related to that of [(C3H7)(4)C5H]Ca-2

引用

页码：11 / 13

页数：3

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