NOVEL REACTION OF BIS(TRIFLUOROMETHYL)DISULFIDE WITH ORGANOLITHIUM REAGENTS

被引：7
|
作者：
MUNAVALLI, S [1 ]
ROSSMAN, DI [1 ]
ROHRBAUGH, DK [1 ]
FERGUSON, CP [1 ]
机构：
[1] GEOCENTERS INC, FT WASHINGTON, MD 20744 USA
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 61卷 / 1-2期
关键词：
D O I：
10.1016/S0022-1139(00)80426-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of bis(trifluoromethyl) disulfide with organolithium reagents at -78-degrees-C results in simultaneous scission of both the C-S and S-S bonds. Under similar conditions, the alkyl and aryl disulfides undergo only S-S bond cleavage. This unusual behavior of bis(trifluoromethyl) disulfide is due to the presence of the trifluoromethyl function. The product distribution, the mechanism of bond fission and the mass spectral data of compounds thus formed are presented in this paper.
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页码：155 / 161
页数：7
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