THE CYCLING PROPERTIES OF THE LIXNI1-YCOYO2 ELECTRODE

被引:333
|
作者
DELMAS, C [1 ]
SAADOUNE, I [1 ]
ROUGIER, A [1 ]
机构
[1] UNIV BORDEAUX 1,ECOLE NATL SUPER PHYS & CHIM,F-33405 TALENCE,FRANCE
关键词
D O I
10.1016/0378-7753(93)80208-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The LiNiO2-LiCoO2 system exhibits a complete solid solution. These materials crystallize in the rhombohedral system with a layered structure. They have been used as positive electrode in lithium batteries. Up to 0.5 lithium atom can be reversibly deintercalated in the 3.5 to 4.0 V potential range. The highest specific energy (close to 500 W h/kg) is obtained in the LixNi0.7Co0.302 system. Moreover, the very small volume change upon deintercalation increased their interest for application point of view.
引用
收藏
页码:595 / 602
页数:8
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