PREPARATION AND MAGNETIC-PROPERTIES OF AL(PF3)(2)

被引：1
|
作者：
HOWARD, JA [1 ]
JONES, R [1 ]
TOMIETTO, M [1 ]
JOLY, HA [1 ]
机构：
[1] LAURENTIAN UNIV,DEPT CHEM & BIOCHEM,SUDBURY,ON P3E 2C6,CANADA
来源：
INORGANIC CHEMISTRY | 1995年 / 34卷 / 11期
关键词：
D O I：
10.1021/ic00115a043
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Al(PF3)(2) is produced by reaction of ground-state Al atoms with PF3 in an adamantane matrix at 77 K in a rotating cryostat. This new Al(0) complex has the magnetic parameters a(Al)(1) = 87 MHz, a(p)(2)= 160 MHz a(F)(6) = MHz, and g = 2.0040, values that are consistent with a(2)B(1) ground-state in C-2v symmetry.
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页码：3097 / 3098
页数：2
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