PREPARATION AND MAGNETIC-PROPERTIES OF AL(PF3)(2)

被引：1

作者：

HOWARD, JA ^{[1
]}

JONES, R ^{[1
]}

TOMIETTO, M ^{[1
]}

JOLY, HA ^{[1
]}

机构：

[1] LAURENTIAN UNIV,DEPT CHEM & BIOCHEM,SUDBURY,ON P3E 2C6,CANADA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 11期

关键词：

D O I：

10.1021/ic00115a043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Al(PF3)(2) is produced by reaction of ground-state Al atoms with PF3 in an adamantane matrix at 77 K in a rotating cryostat. This new Al(0) complex has the magnetic parameters a(Al)(1) = 87 MHz, a(p)(2)= 160 MHz a(F)(6) = MHz, and g = 2.0040, values that are consistent with a(2)B(1) ground-state in C-2v symmetry.

引用

页码：3097 / 3098

页数：2

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