catena-Poly[[(dichloridozinc)-mu-4,4 '-bis(1H-imidazol-1-yl) biphenyl-kappa N-2(3):N-3 ']0.25-hydrate]

被引：2
|
作者：
Ning, Yong-Xia [1 ]
Fan, Wen [1 ]
Xie, Gang [1 ]
机构：
[1] Northwest Univ Xian, Minist Educ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Shaanxi, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1107/S1600536812009543
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title one-dimensional coordination polymer, {[ZnCl2-(C18H14N4)]center dot 0.25H(2)O}(n), the Zn-II atom is coordinated by two chloride ions and two 4,4 '-bis(1H-imidazol-1-yl) biphenyl ligands, generating a distorted tetrahedral ZnCl2N2 geometry. The dihedral angle between the benzene rings of the ligand is 51.0 (1)degrees and the dihedral angles between the benzene rings and their attached imidazole rings are 18.7 (2) and 45.9 (1)degrees. The bridging ligand leads to [10 (1) over bar] polymeric chains in the crystal and the disordered water molecule (occupancy 0.25) forms O-H center dot center dot center dot Cl hydrogen bonds.
引用
收藏
页码：M406 / +
页数：9
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