SYNTHESES, PROPERTIES, AND CRYSTAL AND MOLECULAR-STRUCTURES OF BROMO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II) AND AQUABROMO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II)

被引：13
|
作者：
YAMAGUCHI, H [1 ]
INOMATA, Y [1 ]
TAKEUCHI, T [1 ]
机构：
[1] SOPHIA UNIV,FAC SCI & TECHNOL,DEPT NAT SCI,7-1 KIOICHO,CHIYODA KU,TOKYO 102,JAPAN
来源：
INORGANICA CHIMICA ACTA | 1991年 / 181卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)85256-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The syntheses and characterization of bromo[N,N-bis(2-hydroxyethyl)glycinato]copper(II) (1) and aquabromo[N,N-bis(2-hydroxyethyl)glycinato]copper(II) (2) are presented. X-ray crystal structure determinations of both complexes have been carried out. Complex 1 crystallizes in the monoclinic system, space group P21/n, with Z = 4 and unit cell parameters a = 12.910(2), b = 8.478(1) and c = 8.894(2) angstrom, and beta = 105.11(1)-degrees. Complex 2 crystallizes in the orthorhombic system, space group P2(1)2(1)2(1), with Z = 4 and unit cell parameters a = 8.7672(9), b = 15.594(3) and c = 7.4996(5) angstrom. In complex 1 the copper atom is in a trigonal bipyramidal geometry, while complex 2 has a distorted octahedral configuration.
引用
收藏
页码：31 / 36
页数：6
相关论文
共 50 条
  • [41] Phosphodiester cleavage by lanthanide complexes of N-Bis(2-hydroxyethyl)glycine.
    Calderon, A
    Yatsimirsky, AK
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U665 - U666
  • [42] POLAROGRAPHIC STUDIES OF COPPER(II) COMPLEXES WITH N,N'-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE-N,N'-DIACETIC ACID
    MATSUO, T
    MASUDA, Y
    SEKIDO, E
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 160 (1-2): : 169 - 184
  • [43] Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{N,N-bis(2-hydroxyethyl)glycinate}cadmium(II)
    Katsoulakou, Eugenia
    Konidaris, Konstantis F.
    Raptopoulou, Catherine P.
    Psyharis, Vassilis
    Manessi-Zoupa, Evy
    Perlepes, Spyros P.
    [J]. BIOINORGANIC CHEMISTRY AND APPLICATIONS, 2010, 2010
  • [44] USE OF N,N-BIS(2-HYDROXYETHYL)DITHIO-OXAMIDE IN VOLUMETRIC DETERMINATION OF NICKEL AND NICKEL-COPPER MIXTURES
    WILLS, V
    STAMBAUGH, OF
    PROCTOR, ZG
    [J]. ANALYTICAL CHEMISTRY, 1963, 35 (02) : 257 - &
  • [45] Mixed-ligand complex formation equilibria of cobalt(II), nickel(II), and copper(II) with N,N-bis(2-hydroxyethyl)glycine (bicine) and some amino acids
    Taha, M
    Khalil, MM
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (01): : 157 - 163
  • [46] STRUCTURE OF BIS[N,N-BIS(2-HYDROXYETHYL)DITHIOCARBAMATO]NICKEL(II), C10H20N2NIO4S4
    RAMALINGAM, K
    RADHA, K
    ARAVAMUDAN, G
    MAHADEVAN, C
    SUBRAMANYAM, C
    SESHASAYEE, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (NOV) : 1838 - 1839
  • [47] Surface active properties of N,N-bis(2-hydroxyethyl) fatty amides derived from pilu fat
    Patel, RP
    Mannari, VM
    [J]. JOURNAL OF SCIENTIFIC & INDUSTRIAL RESEARCH, 1997, 56 (11): : 686 - 690
  • [48] NEW COMPLEXANES .44. POTENTIOMETRIC STUDY OF CHELATE FORMATION OF N,N-BIS(2-HYDROXYETHYL)GLYCINE AND D,L-N,N-BIS(2-HYDROXYETHYL)-ALPHA-ALANINE WITH RARE-EARTH ELEMENTS
    RIECANSKA, E
    FULEOVA, E
    MAJER, J
    [J]. CHEMICKE ZVESTI, 1982, 36 (04): : 501 - 506
  • [49] STRUCTURE OF N,N'-BIS(2-HYDROXYETHYL)PIPERAZINE
    OKAMOTO, K
    FUJII, S
    TOMITA, K
    ARAI, S
    TSUTSUMI, Y
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1518 - 1519
  • [50] Streptomycin release from N,N-bis(2-hydroxyethyl) fatty amide modified polymeric coating
    Raval, DA
    Patel, VM
    Parikh, DN
    [J]. REACTIVE & FUNCTIONAL POLYMERS, 2006, 66 (03): : 315 - 321
12345