ELECTRON-TRANSFER IN MOLECULES WITH CONFORMATIONAL TRANSITIONS

被引：14
|
作者：
MATYUSHOV, DV
机构：
[1] Institute of General and Inorganic Chemistry, 252142 Kiev
来源：
CHEMICAL PHYSICS LETTERS | 1993年 / 203卷 / 2-3期
关键词：
D O I：
10.1016/0009-2614(93)85376-Y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Intramolecular electron transfer reactions are considered with regard to conformational transitions in a molecule containing a donor and an acceptor. It is shown that the free energy of activation contains. besides the activation enthalpy, a temperature-dependent entropic term DELTAS = a1 + a2T.
引用
收藏
页码：131 / 136
页数：6
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