ELECTRON-TRANSFER IN MOLECULES WITH CONFORMATIONAL TRANSITIONS

被引：14

作者：

MATYUSHOV, DV

机构：

[1] Institute of General and Inorganic Chemistry, 252142 Kiev

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 203卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(93)85376-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Intramolecular electron transfer reactions are considered with regard to conformational transitions in a molecule containing a donor and an acceptor. It is shown that the free energy of activation contains. besides the activation enthalpy, a temperature-dependent entropic term DELTAS = a1 + a2T.

引用

页码：131 / 136

页数：6

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