DOUBLE SALTS OBTAINED FROM ME(+)X-CUX(2)-H2O SYSTEMS (ME(+)=K+, NH4+, RB+, CS+, X(-)=CL-, BR-)

被引：12
|
作者：
TEPAVITCHAROVA, S
BALAREW, C
TRENDAFILOVA, S
机构：
[1] Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 114卷 / 02期
关键词：
D O I：
10.1006/jssc.1995.1059
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The solubility diagrams of the Me(+)Br-CuBr2-H2O (Me(+) = K+ NH4+, Rb+, Cs+) systems are studied. The results obtained are compared with literature data on the corresponding chloride systems in order to estimate the effect of the halide ion (Br- or Cl-) on the solubility diagrams and on the compositions of the double salts formed in these systems. The differences in composition and structure of the double salts are explained by the metal-ligand interactions on the basis of Pearson's concept of hard and soft Lewis acids and bases, as well as by crystal chemistry considerations for the most probable spacial situation of the building elements in the crystal structure. (C) 1995 Academic Press, Inc.
引用
收藏
页码：385 / 391
页数：7
相关论文
共 50 条
  • [21] Thermodynamic properties and NMR study of tetragonal tetrahalogen-metallate dihydrate crystals of Rb2[CuX4]•2H2O (X=Cl- and Br-)
    Lim, Ae Ran
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2018, 134 (02) : 1145 - 1150
  • [22] State of uranyl arsenates MIAsUO6·nH2O (MI–H+, Li+, Na+, K+, Rb+, Cs+, NH4+) in aqueous solution
    Oxana V. Nipruk
    Nikolay G. Chernorukov
    Elena V. Elipasheva
    Kseniya A. Klinshova
    Maxim O. Bakhmetev
    Journal of Radioanalytical and Nuclear Chemistry, 2020, 324 : 233 - 244
  • [23] State of uranyl arsenates MIAsUO6•nH2O (MI-H+, Li+, Na+, K+, Rb+, Cs+, NH4+) in aqueous solution
    Nipruk, Oxana V.
    Chernorukov, Nikolay G.
    Elipasheva, Elena V.
    Klinshova, Kseniya A.
    Bakhmetev, Maxim O.
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2020, 324 (01) : 233 - 244
  • [24] FURTHER NEIGHBOR INTERACTIONS IN QUASI BCC HEISENBERG FERROMAGNETS M2CUX4 . 2H2O(M=NH4,K,RB OR CS-X=CL OR BR)
    VANAMSTEL, WD
    DEJONGH, LJ
    MATSUURA, M
    SOLID STATE COMMUNICATIONS, 1974, 14 (06) : 491 - 496
  • [25] Phase diagrams for the partial systems of the quaternary reciprocal system K+,NH4+ parallel Cl-,Br--H2O at 25°C
    Rumyantsev, A.V.
    Charykov, N.A.
    Zamoryanskaya, M.V.
    Arapov, O.V.
    Charykova, M.V.
    Shakhmatkin, B.A.
    Zhurnal Neorganicheskoj Khimii, 2003, 48 (11): : 1887 - 1898
  • [26] A Thermodynamic Model for the NH4+, K+ // H2PO4-, H2P2O72-, NO3-, Cl- - H2O System
    Chartrand, Patrice
    Gemme, Frederic
    Robelin, Christian
    SYMPHOS 2013 - 2ND INTERNATIONAL SYMPOSIUM ON INNOVATION AND TECHNOLOGY IN THE PHOSPHATE INDUSTRY, 2014, 83 : 250 - 258
  • [27] Hydrogen-bonded (H2O•X)2 [X=Cl-, Br-] clusters in 1-phenacyl-4-(dimethylamino)pyridinium halide monohydrates
    Prabakaran, P
    Muthiah, PT
    Nallu, M
    Sathiskumar, V
    Bocelli, G
    Righi, L
    JOURNAL OF CHEMICAL RESEARCH, 2001, (06) : 248 - 249
  • [28] THE FORMATION OF HAFNIUM DOUBLE SULFATES IN THE HFO2-H2SO4-H2O(ME-NA, K, RB, CS AND NH4) SYSTEMS
    MOTOV, DL
    SOZINOVA, YP
    ZHURNAL NEORGANICHESKOI KHIMII, 1982, 27 (12): : 3194 - 3197
  • [29] Effect of the degree of copper oxidation on solubility in CuX(n)-KX-H2O systems where (X(-)=Cl-, Br-, I-)
    Chernykh, LV
    Skripkin, MY
    ZHURNAL OBSHCHEI KHIMII, 1996, 66 (01): : 26 - 30
  • [30] Investigations on the spin Hamiltonian parameters and the local structures for the orthorhombic [CuX4(H2O)2]2- centers in NH4X (X = Cl, Br)
    Zhang, Hua-Ming
    Wu, Shao-Yi
    Kuang, Min-Quan
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2012, 984 : 137 - 141
12345