A TITANIUM-MAGNESIUM COMPLEX CONTAINING PERPENDICULARLY BRIDGING BIS(TRIMETHYL-SILYL)ACETYLENE LIGANDS - [(ETA-5-C5H5)TI][ETA-5-C5H5)MG][MU-ETA-2-ETA-2-C2(SIME3)2]2

被引：13

作者：

VARGA, V

MACH, K

SCHMID, G

THEWALT, U

机构：

[1] ACAD SCI CZECH REPUBL, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, DOLEJSKOVA 3, CS-18223 PRAGUE 8, CZECHOSLOVAKIA

[2] UNIV ULM, DEPT XRAY & ELECTRON DIFFRACT, W-7900 ULM, GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 454卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83253-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [eta5-C5H5)Ti][eta5-C5H5)Mg][mu-eta2(Ti, Mg): eta2(Ti, Mg)-C2(SiMe3)2]2 (1) was obtained by the reaction of (eta5-C5H5)2Ti(eta-C2(SiMe3)2) (2) with Mg and bis(trimethylsilyl)acetylene in THF. Crystals of 1 contain two slightly different molecules in the asymmetric unit. Both molecules contain Ti and Mg atoms in the apical positions of a nearly symmetrical rectangular bipyramid whose base is formed by four equivalent acetylenic carbons atoms. Each metal atom is capped by one eta5-C5H5 ligand.

引用

页码：C1 / C4

页数：4

共 50 条

[41] A MOSSBAUER SPECTROSCOPIC STUDY OF [(ETA-5-C5H5)2FE]+[(NC)2C=C(CN)O]-.[(ETA-5-C5H5)2FE]1/2
ROBERTS, RMG
SILVER, J
[J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 102 (01): : 51 - 53
[42] DICARBONYL(ETA-5-CYCLOPENTADIENYL)(THIOCARBONYL)IRON(1+) TRIFLUOROMETHANESULFONATE(1-) AND DICARBONYL(ETA-5-CYCLOPENTADIENYL)[(METHYLTHIO)THIOCARBONYL]IRON [(ETA-5-C5H5)2FE2(CO)4] + NA HG-]2[(ETA-5-C5H5)FE(CO)2]- [(ETA-5-C5H5)FE(CO)2]- + CS2-][(ETA-5-C5H5)FE(CO)2(CS2)]- [(ETA-5-C5H5)FE(CO)2(CS2)]- + CH3I-](ETA-5-C5H5)FE(CO)2[(CS)SCH3] + I- (ETA-5-C5H5)FE(CO)2[(CS)SCH3] + CF3SO3H-][(ETA-5-C5H5)FE(CO)2(CS)]+[SO3CF3]- + CH3SH
DOMBEK, BD
CHOI, MG
ANGELICI, RJ
[J]. INORGANIC SYNTHESES, 1990, 28 : 186 - 189
[43] CATIONIC COMPLEXES WITH (ETA-5-C5H5)2TIIV COMPONENT GROUPS - SYNTHESIS AND STRUCTURE OF "[(ETA-5-C5H5)2TI(BIPY)]2+(CF3SO3-)2 AND "[(ETA-5-C5H5)2TI(PHEN)]2+(CF3SO3-)2
THEWALT, U
BERHALTER, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 302 (02) : 193 - 200
[44] INNER-SHELL SPECTROSCOPY OF (ETA-5-C5H5)2TICL2, (ETA-5-C5H5)TICL3, AND TICL4
WEN, AT
HITCHCOCK, AP
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1993, 71 (10): : 1632 - 1644
[45] ETA-3-ALLYL COMPLEXES OF MOLYBDENUM - THE PREPARATION AND STRUCTURE OF [MO(ETA-3-C3H5)2(ETA-5-C5H5)]
JOLLY, PW
KRUGER, C
ROMAO, CC
ROMAO, MJ
[J]. ORGANOMETALLICS, 1984, 3 (06) : 936 - 937
[46] TRIPLE-DECKER COMPLEXES .14. REACTIONS OF IRON CARBONYLS WITH THE TRIPLE-DECKER SANDWICH COMPLEXES (ETA-5-C5H5)NI(MU,ETA-5-C2B2C)M(ETA-5-C5H5), (M = CO, NI) - REPLACEMENT OF (ETA-5-C5H5)NI BY AND INSERTION OF THE FE(CO)3 FRAGMENT INTO THE (ETA-5-C5H5)-NI BOND
EDWIN, J
WHITELEY, MW
HERTER, W
SIEBERT, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 394 (1-3) : 329 - 338
[47] STRUCTURAL STUDIES OF (ETA-5-C5H5)2NB(SC6H5)2, [(ETA-5-C5H5)2NB(SC6H5)2+], AND [(ETA-5-C5H5)2NB(MU-SC6H5)2MO(CO)4+]
DARENSBOURG, MY
SILVA, R
REIBENSPIES, J
PROUT, CK
[J]. ORGANOMETALLICS, 1989, 8 (05) : 1315 - 1323
[48] HETEROBIMETALLIC MU-(ETA-1-C-ETA-2-O,O') CARBON-DIOXIDE COMPLEXES (ETA-5-C5H5) (CO)2M - CO2-M'(CL)ETA-5-C5H5)2(M=FE,RU,M'=TI,ZR)
VITES, JC
DERY, ME
CUTLER, AR
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 198 : 34 - INOR
[49] STRUCTURE OF (CL)(NO)2CR(ETA-5-C5H4)C(O)(ETA-5-C5H4)FE(ETA-5-C5H5)
WANG, YP
HWU, JM
WANG, SL
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 2305 - 2308
[50] CHARACTERIZATION OF THE HETEROBIMETALLIC MU-(ETA-1-C-ETA-2-O,O') CARBON-DIOXIDE COMPLEXES (ETA-5-C5H5)(CO)2MCO2M'(CL)(ETA-5-C5H5)2(M=FE,RU, M'=TI,ZR)
VITES, JC
STEFFEY, BD
GIUSEPPETTIDERY, ME
CUTLER, AR
[J]. ORGANOMETALLICS, 1991, 10 (08) : 2827 - 2834

← 1 2 3 4 5 →