THE INTERMOLECULAR DIELS-ALDER REACTION OF A 14-MEMBERED DIENE-DIENOPHILE PAIR

被引：0
|
作者：
NAKATA, M [1 ]
YASUDA, M [1 ]
SUZUKI, S [1 ]
OHBA, S [1 ]
机构：
[1] KEIO UNIV,DEPT CHEM,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN
来源：
SYNLETT | 1994年 / 01期
关键词：
DIELS-ALDER REACTION; 14-MEMBERED DIENE-DINENOPHILE PAIR; DIETHYLALUMINUM CHLORIDE; METHYL SARCOPHYTOATE; BISCEMBRANOIDS;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The intermolecular Diels-Alder reaction between methyl 3-oxo-1-cyclotetradecenecarboxylate (5) and (1E,3E)-1-isopropenyl-1,3-cyclotetradecadiene (6) has been investigated. The structures of the adducts under the Et(2)AlCl-promoted conditions and the thermal conditions were determined by H-1 NMR and X-ray crystallographic analyses.
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页码：71 / 74
页数：4
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