(E)-2-((4R, 5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol

被引：1
|
作者：
Carreras, Carlos R. [1 ]
Garcia, Celina E. [2 ]
Martin, Victor S. [2 ]
Tonn, Carlos E. [1 ]
Diaz Diaz, David [3 ,4 ]
Pedro Cenal, Juan [1 ]
机构：
[1] Univ Nacl San Luis, Fac Quim Bioquim & Farm, INTEQUI CONICET, San Luis, Argentina
[2] Univ La Laguna, Inst Univ Bioorgan Antonio Gonzalez, Tenerife 38206, Spain
[3] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany
[4] Univ Zaragoza, CSIC, ICMA, E-50009 Zaragoza, Spain
来源：
MOLBANK | 2010年 / 02期
关键词：
reduction; DIBAL-H; substituted butenolides; allylic diols;
D O I：
10.3390/M676
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of (E)-2-((4R,5R)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol by a one-step reduction of the appropriate 2-substituted butenolide is reported. Product characterization was carried out by IR, H-1 NMR, C-13 NMR, MS, elemental analysis and optical rotation.
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页数：4
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