MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .133. METHYLTRIOXORHENIUM AS A CATALYST OF THE BAEYER-VILLIGER OXIDATION

被引：104
|
作者：
HERRMANN, WA
FISCHER, RW
CORREIA, JDG
机构：
[1] Anorganisch-chemisches Institut der Technischen Universität München, D-85747 Garching
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 94卷 / 02期
关键词：
BAEYER-VILLIGER REACTION; LACTONES; OXIDATION; RHENIUM;
D O I：
10.1016/S0304-5102(94)87043-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Methyltrioxorhenium CH3ReO3 (MTO, 1) is one of the most active catalysts of the Baeyer-Villiger oxidation of cyclic ketones by use of H2O2 as oxidant. In contrast to the chemistry of established molybdenum and tungsten peroxo complexes, the bis(peroxo) complex [CH3ReO(O-2)(2).H2O] reacts stoichiometrically with ketones. The electronic character of the active species was determined by spectroscopy and by application of an oxygen transfer probe.
引用
收藏
页码：213 / 223
页数：11
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