ANALYTICAL DEPENDENCE OF THE VISCOSITY CROSS-SECTIONS AND VISCOSITY COEFFICIENTS ON PARAMETERS OF INTERMOLECULAR POTENTIALS

被引:9
|
作者
KUNC, JA
机构
[1] HARVARD UNIV,INST THEORET ATOM & MOLEC PHYS,CAMBRIDGE,MA 02138
[2] HARVARD SMITHSONIAN CTR ASTROPHYS,CAMBRIDGE,MA 02138
来源
JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 06期
关键词
D O I
10.1063/1.466068
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
General analytical expressions for viscosity cross sections and viscosity coefficients of gases as functions of the parameters of intermolecular potentials are derived from the first principle using the classical scattering theory. Two types (one repulsive-attractive and one purely repulsive) of the central-force potentials, suitable to represent molecule-molecule, atom-molecule and atom-atom interactions, are considered. The expressions for viscosity show good agreement with results of numerical calculations in high-temperature single-component gases (above 2000 K) where viscosity measurements are not available.
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页码:4705 / 4717
页数:13
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