A STUDY OF THE BEHAVIOR OF POLY(N-VINYLCARBAZOLE) IN BINARY-MIXTURES OF TETRAHYDROFURAN AND POLY(ETHYLENE GLYCOL) OLIGOMERS

被引：1

作者：

CESTEROS, LC ^{[1
]}

VAZQUEZ, Y ^{[1
]}

RABANAL, N ^{[1
]}

KATIME, I ^{[1
]}

机构：

[1] UNIV BASQUE COUNTRY, FAC CIENCIAS,DEPT QUIM FIS,NUEVOS MAT GRP, APARTADO 644, BILBAO, SPAIN

来源：

POLYMER | 1990年 / 31卷 / 10期

关键词：

miscibility; PEG oligomers; PNVK; preferential solvation; total;

D O I：

10.1016/0032-3861(90)90009-N

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this paper we report studies on poly(N-vinylcarbazole) (PNVK) in binary mixtures of THF (1) and poly(ethylene glycol) (2) obtained by viscometry and laser light scattering measurements. From these data, total and preferential solvation parameters were calculated over the whole binary mixture composition range studied. We have not found any inversion in the solvation. Inter- and intra-molecular interactions, Kθ and B, were calculated using the Stockmayer-Fixman equation. Finally, we found that the compatibility between PNVK and PEG increases linearly as PEG molar mass increases. © 1990.

引用

页码：1871 / 1876

页数：6

共 50 条

[21] PHOTOCARRIER GENERATION IN POLY (N-VINYLCARBAZOLE)
PFISTER, G
WILLIAMS, DJ
BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1974, 19 (03): : 330 - 330
[22] HOLE PHOTOGENERATION IN POLY(N-VINYLCARBAZOLE)
BORSENBERGER, PM
ATEYA, AI
JOURNAL OF APPLIED PHYSICS, 1978, 49 (07) : 4035 - 4040
[23] CHEMICAL MODIFICATION OF POLY(N-VINYLCARBAZOLE)
PIELICHOWSKI, J
MORAWIEC, E
JOURNAL OF APPLIED POLYMER SCIENCE, 1976, 20 (07) : 1803 - 1812
[24] A synthesis technology of poly(N-vinylcarbazole)
Dai, Ya-Jie
Dong, Wei
Zhang, Wen-Long
Wang, Xuan
Zhao, Hong
Bai, Yong-Ping
Cailiao Kexue yu Gongyi/Material Science and Technology, 2009, 17 (05): : 632 - 635
[25] PHOTOGENERATION PROCESSES IN POLY (N-VINYLCARBAZOLE)
PFISTER, G
WILLIAMS, DJ
JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (06): : 2416 - 2426
[26] Synthesis of uniform hollow poly(N-vinylcarbazole) and liquid crystal/poly(N-vinylcarbazole) core/shell nanoparticles
Jung, Yuri
Choi, Jongwan
Oh, Jin-Woo
Kim, Nakjoong
SYNTHETIC METALS, 2013, 163 : 24 - 28
[27] THERMAL-CONDUCTIVITY OF POLY(ETHYLENE GLYCOLS) AND THEIR BINARY-MIXTURES
DIGUILIO, R
TEJA, AS
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1990, 35 (02): : 117 - 121
[28] A conducting nanocomposite of poly(N-vinylcarbazole) with buckminsterfullerene
Biswas, M
Ray, SS
SYNTHETIC METALS, 2001, 123 (01) : 135 - 139
[29] EXCIMER DYNAMICS IN POLY(N-VINYLCARBAZOLE) FILMS
MASUHARA, H
TAMAI, N
IKEDA, N
MATAGA, N
ITAYA, A
OKAMOTO, K
KUSABAYASHI, S
CHEMICAL PHYSICS LETTERS, 1982, 91 (02) : 113 - 116
[30] STUDY OF ELECTROCHEMICALLY DEPOSITED THIN POLY(N-VINYLCARBAZOLE) FILMS
TOPART, PA
JOSOWICZ, M
TALANTA, 1994, 41 (06) : 909 - 916

← 1 2 3 4 5 →