MODELING THE KINETICS OF THE PRECIPITATION POLYMERIZATION OF ACRYLIC-ACID

被引：16
|
作者：
AVELA, A
POERSCH, HG
REICHERT, KH
机构：
[1] Institut für Technische Chemie, Technische Universität Berlin, Berlin, D-1000
来源：
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1990年 / 175卷
关键词：
D O I：
10.1002/apmc.1990.051750109
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A kinetic model for the free‐radical precipitation polymerization of acrylic acid in toluene was developed and verified experimentally by using an isothermal reaction calorimeter. The model predicts the rate of polymerization accurately up to complete conversion in the temperature range of 40 to 60°C. © 1990 Hüthig & Wepf Verlag, Basel
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页码：107 / 116
页数：10
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