DISPERSION POLYMERIZATION OF STYRENE IN AQUEOUS ALCOHOL SOLUTION - EFFECTS OF REACTION PARAMETERS ON THE POLYMER PARTICLE FORMATION

被引：30

作者：

UYAMA, H ^{[1
]}

KOBAYASHI, S ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC ENGN,DEPT MOLEC CHEM & ENGN,SENDAI,MIYAGI 980,JAPAN

来源：

POLYMER INTERNATIONAL | 1994年 / 34卷 / 03期

关键词：

DISPERSION POLYMERIZATION; MONODISPERSE PARTICLE; POLY(2-ETHYL-2-OXAZOLINE); STABILIZER;

D O I：

10.1002/pi.1994.210340315

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dispersion polymerization of styrene in an aqueous alcohol solution using poly(2-ethyl-2-oxazoline) as a polymeric stabilizer was performed to prepare micron-size monodisperse polystyrene particles. As the water content of the solvent increased, the polymerization rate and the molecular weight of the polymer particles increased and the particle size decreased. Effects of concentrations of stabilizer and initiator upon the polymerization and the size of the resulting polystyrene particles have been examined in the solvent containing different water contents.

引用

页码：339 / 344

页数：6

共 50 条

[21] CONTROLLED/"LIVING" RADICAL POLYMERIZATION OF STYRENE IN AN AQUEOUS DISPERSION SYSTEM
Bin Zhang
Zhao-bin Zhang
Xiao-long Wan
Chun-pu Hu
Sheng-kang Ying Lab of Living Polymerization
Chinese Journal of Polymer Science, 2002, (05) : 445 - 451
[22] Controlled/"living" radical polymerization of styrene in an aqueous dispersion system
Zhang, B
Zhang, ZB
Wan, XL
Hu, CP
Ying, SK
CHINESE JOURNAL OF POLYMER SCIENCE, 2002, 20 (05) : 445 - 451
[23] A CATIONIC POLYACRYLAMIDE DISPERSION SYNTHESIS BY DISPERSION POLYMERIZATION IN AQUEOUS SOLUTION
Wang, Yufeng
Chen, Kefu
Mo, Lihuan
Hu, Huiren
BIORESOURCES, 2011, 6 (03): : 3087 - 3095
[24] Emulsion polymerization of tetrafluoroethylene: effects of reaction conditions on particle formation
Kim, CU
Lee, JM
Ihm, SK
JOURNAL OF FLUORINE CHEMISTRY, 1999, 96 (01) : 11 - 21
[25] Particle size effects in TEMPO-mediated radical polymerization of styrene in aqueous miniemulsion
Nakamura, Tadashi
Zetterlund, Per B.
Okubo, Masayoshi
MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (23) : 2014 - 2018
[26] Effect of reaction parameters on the particle size in the dispersion polymerization of 2-hydroxyethyl methacrylate
Horák, D
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (20) : 3785 - 3792
[27] FORMATION OF NON-AQUEOUS POLYMER DISPERSIONS DURING THE POLYMERIZATION OF STYRENE IN HEPTANE SOLUTIONS OF POLYDIMETHYLSILOXANE
BRYK, MT
AGEEVA, IA
ILINA, ZT
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1980, 22 (12): : 2700 - 2705
[28] Crosslinking network structure effects on particle coagulation in the emulsion polymerization of styrene in methanol solution
Baijun Liu
Mingyao Zhang
Yuhui Ao
Huixuan Zhang
Colloid and Polymer Science, 2015, 293 : 1577 - 1581
[29] Crosslinking network structure effects on particle coagulation in the emulsion polymerization of styrene in methanol solution
Liu, Baijun
Zhang, Mingyao
Ao, Yuhui
Zhang, Huixuan
COLLOID AND POLYMER SCIENCE, 2015, 293 (05) : 1577 - 1581
[30] HYDROXYPROPYL CELLULOSE (HPC)-STABILIZED DISPERSION POLYMERIZATION OF STYRENE IN POLAR-SOLVENTS - EFFECT OF REACTION PARAMETERS
CHEN, Y
YANG, HW
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (13) : 2765 - 2772

← 1 2 3 4 5 →