REDUCTIVE DEHALOGENATION OF ALPHA-HALOKETONES PROMOTED BY HYDROIODIC ACID AND WITHOUT SOLVENT

被引：15

作者：

PENSO, M ^{[1
]}

MOTTADELLI, S ^{[1
]}

ALBANESE, D ^{[1
]}

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 10期

关键词：

D O I：

10.1080/00397919308011227

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several alpha-haloketones have been transformed into the corresponding ketones by reaction with aqueous 57% HI, without solvent. The products are obtained in nearly quantitative yields and with high purity (>99%) even in the case of sterically hindered starting materials.

引用

页码：1385 / 1391

页数：7

共 26 条

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[17] CARBON-CARBON DOUBLE-BOND FORMATION BETWEEN ALPHA-HALOKETONES AND ALDEHYDES PROMOTED BY SAMARIUM TRIIODIDE
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TETRAHEDRON LETTERS, 1993, 34 (28) : 4547 - 4550
[18] ACID-CATALYZED ELECTRON-TRANSFER PROCESSES IN REDUCTION OF ALPHA-HALOKETONES BY AN NADH MODEL-COMPOUND AND FERROCENE DERIVATIVES
FUKUZUMI, S
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (04) : 1497 - 1499
[19] MECHANISM OF EPIMERISATION OF ALPHA-HALOKETONES .I. STEREOSELECTIVE SYNTHESIS OF 2-HALO-4-TERBUTYL CYCLOHEXANONES . EPIMERISATION IN ACID MEDIUM
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